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SYNTHESIS AND CHARACTERIZATION OF BIDENTATE CYCLOTRIPHOSPHAZENE DERIVATIVES
Han, Rui ; Ren, Xue-lin ; Zhang, Di ; Wang, Min ; Yang, Jun-liang ; Ye, Yong ; Zhao, Yufen ; Zhao YF(赵玉芬)
刊名http://dx.doi.org/10.1080/10426507.2011.583617
2011
关键词PHYSICAL-PROPERTIES SIDE-GROUPS PHOSPHAZENES PHOSPHORUS POLYMERS
英文摘要NSFC [20602032, 20732004, 20972143]; Three novel cyclotriphosphazene derivatives were designed. Title compounds were synthesized by the reaction of the dichlorocyclotriphosphazene derivative [N3P3Cl2(O2C12H8)(2)] with the potassium salt of 4-hydroxybenzaldehyde, and subsequent reduction of aldehyde groups to alcohol groups using sodium borohydride. The bromination reaction was carried out using PBr3 to give N3P3(O2C12H8)(2) (OC6H4-p-CH2Br)(2). This compound was employed in reactions with macrocyclic polyamide, imidazole, or morpholine to produce title compounds. The target compounds were characterized using H-1 NMR, P-31 NMR, C-13 NMR, IR, and electrospray ionization mass spectra (ESI-MS). [Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental resource: Figures S1-S6.]
语种英语
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/63760]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Han, Rui,Ren, Xue-lin,Zhang, Di,et al. SYNTHESIS AND CHARACTERIZATION OF BIDENTATE CYCLOTRIPHOSPHAZENE DERIVATIVES[J]. http://dx.doi.org/10.1080/10426507.2011.583617,2011.
APA Han, Rui.,Ren, Xue-lin.,Zhang, Di.,Wang, Min.,Yang, Jun-liang.,...&赵玉芬.(2011).SYNTHESIS AND CHARACTERIZATION OF BIDENTATE CYCLOTRIPHOSPHAZENE DERIVATIVES.http://dx.doi.org/10.1080/10426507.2011.583617.
MLA Han, Rui,et al."SYNTHESIS AND CHARACTERIZATION OF BIDENTATE CYCLOTRIPHOSPHAZENE DERIVATIVES".http://dx.doi.org/10.1080/10426507.2011.583617 (2011).
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