General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants | |
Liu, X. W. ; Zhang, Y. M. ; Wang, L. ; Fu, H. ; Jiang, Y. Y. ; Zhao, Y. F. ; Zhao YF(赵玉芬) | |
2008 | |
关键词 | CARBON-HYDROGEN BONDS CHLORAMINE-T NITROGEN ATOM BROMAMINE-T INTRAMOLECULAR AMIDATION NITRENE SOURCE AMINATION AZIRIDINATION FUNCTIONALIZATION ACTIVATION |
英文摘要 | We have developed a general and efficient method for copper-catalyzed amidation of saturated C-H bonds under mild conditions, and the used substrates include benzylic reagents, the N,N-dimethylaniline derivatives, the free carboxamides, and sulfonamides. The protocol uses inexpensive and readily available CuBr/N-halosuccinimide (NBS or NCS) as the catalyst/oxidant, so it provides practical applications for synthesis of various amides via C-H activation. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/63660] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Liu, X. W.,Zhang, Y. M.,Wang, L.,et al. General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants[J],2008. |
APA | Liu, X. W..,Zhang, Y. M..,Wang, L..,Fu, H..,Jiang, Y. Y..,...&赵玉芬.(2008).General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants.. |
MLA | Liu, X. W.,et al."General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants".(2008). |
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