Adsorption and reaction at electrochemical interfaces as probed by surface-enhanced Raman spectroscopy

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	Adsorption and reaction at electrochemical interfaces as probed by surface-enhanced Raman spectroscopy
	Tian, Z. Q. ; Ren, B. ; Tian ZQ(田中群)
刊名	http://dx.doi.org/10.1146/annurev.physchem.54.011002.103833
	2004
关键词	TRANSITION-METAL INTERFACES ELECTRODE SURFACES PLATINUM-ELECTRODES SILVER ELECTRODE SINGLE-MOLECULE INFRARED-SPECTROSCOPY NEUTRON REFLECTIVITY HYDROGEN EVOLUTION METHANOL OXIDATION NICKEL ELECTRODES
英文摘要	Over the past three decades, surface-enhanced Raman spectroscopy (SERS) has gone through a tortuous pathway to develop into a powerful surface diagnostic technique for in situ investigation of surface adsorption and reactions on electrodes. This review presents the recent progress achieved mainly in our laboratory on the improvement of detection sensitivities as well as spectral, temporal, and spatial resolutions. Various surface roughening procedures for electrodes of different metals coupled with maximum use of a high-sensitivity confocal Raman microscope enable us to obtain good-quality SER spectra on the electrode surfaces made from net Pt, Ni, Co, Fe, Pd, Rh, Ru, and their alloys that were traditionally considered to be non-SERS active. A novel technique called potential-averaged SERS (PASERS) has been developed for the quantitative study of electrochemical sorption. Applications are exemplified on extensively studied areas such as coadsorption, electrocatalysis, corrosion, and fuel cells, and several advantages of in situ electrochemical SERS are demonstrated. Finally, further developments in this field are briefly discussed with emphasis on the emerging methodology.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/63011]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Tian, Z. Q.,Ren, B.,Tian ZQ. Adsorption and reaction at electrochemical interfaces as probed by surface-enhanced Raman spectroscopy[J]. http://dx.doi.org/10.1146/annurev.physchem.54.011002.103833,2004.
APA	Tian, Z. Q.,Ren, B.,&田中群.(2004).Adsorption and reaction at electrochemical interfaces as probed by surface-enhanced Raman spectroscopy.http://dx.doi.org/10.1146/annurev.physchem.54.011002.103833.
MLA	Tian, Z. Q.,et al."Adsorption and reaction at electrochemical interfaces as probed by surface-enhanced Raman spectroscopy".http://dx.doi.org/10.1146/annurev.physchem.54.011002.103833 (2004).