Directional surface plasmon-coupled emission of CdTe quantum dots and its application in Hg(II) sensing | |
Liu, Xiao-Qing ; Liu, Qian ; Cao, Shuo-Hui ; Cai, Wei-Peng ; Weng, Yu-Hua ; Xie, Kai-Xin ; Li, Yao-Qun ; Li YQ(李耀群) | |
刊名 | http://dx.doi.org/10.1039/c2ay25541c |
2012 | |
关键词 | MEMBRANE-PROTEIN SYSTEMS WHOLE-BLOOD RESONANCE SPECTROSCOPY BIOPHYSICAL PROPERTIES AQUEOUS SYNTHESIS NANOCRYSTALS LUMINESCENCE SENSITIVITY PROBES FILMS |
英文摘要 | National Natural Science Foundation of China [21127005, 20975084]; Ph.D. Programs Foundation of the Ministry of Education of China [20110121110011]; We investigated the surface plasmon-coupled emission (SPCE) of CdTe quantum dots (QDs) and developed an SPCE-based quenchometric sensor for Hg(II) ion sensing. CdTe QDs directly synthesized in aqueous solution were attached to a 50 nm-thick Au film through layer-by-layer assembly. The directional emission of the CdTe QDs on the prism side from the surface plasmon coupling was completely p-polarized and observed at a fixed angle of 48.5 degrees, which was consistent with theoretical calculations. An SPCE-based quenchometric sensor for Hg(II) ion sensing was established based on the quenching effect of Hg(II) ions on the fluorescence emission of CdTe QDs. As expected, the SPCE-based sensor enlarged the response range and was more sensitive than that based on free-space detection as a result of the high light-collection efficiency of SPCE. QDs with excellent properties combined with SPCE technology have great potential in detecting analytes at low concentration levels. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/62229] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Liu, Xiao-Qing,Liu, Qian,Cao, Shuo-Hui,et al. Directional surface plasmon-coupled emission of CdTe quantum dots and its application in Hg(II) sensing[J]. http://dx.doi.org/10.1039/c2ay25541c,2012. |
APA | Liu, Xiao-Qing.,Liu, Qian.,Cao, Shuo-Hui.,Cai, Wei-Peng.,Weng, Yu-Hua.,...&李耀群.(2012).Directional surface plasmon-coupled emission of CdTe quantum dots and its application in Hg(II) sensing.http://dx.doi.org/10.1039/c2ay25541c. |
MLA | Liu, Xiao-Qing,et al."Directional surface plasmon-coupled emission of CdTe quantum dots and its application in Hg(II) sensing".http://dx.doi.org/10.1039/c2ay25541c (2012). |
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