Rh-catalyzed syngas conversion to ethanol: Studies on the promoting effect of FeOx

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	Rh-catalyzed syngas conversion to ethanol: Studies on the promoting effect of FeOx
	Wang, Jingjuan ; Zhang, Qinghong ; Wang, Ye ; Zhang QH(张庆红)
刊名	http://dx.doi.org/10.1016/j.cattod.2011.03.023
	2011-08-10
关键词	RH/SIO2 CATALYSTS SUPPORTED RHODIUM DIMETHYL ETHER SYNTHESIS GAS SELECTIVITY METHANE OXIDES
英文摘要	National Natural Science Foundation of China [20873110, 20923004, 21033006]; National Basic Program of China [2010CB732303]; Research Fund for the Doctoral Program of Higher Education [20090121110007]; Key Scientific Project of Fujian Province [2009HZ0002; Rhodium catalysts loaded on silica modified by various transition metal oxides were investigated for the conversion of syngas to ethanol. Iron oxide was found to be an efficient promoter for ethanol formation. The increase in iron content up to 5 wt% significantly increased CO conversion and ethanol selectivity. The preparation method used for introducing FeOx was found to affect both the conversion and the selectivity significantly. The catalyst prepared by the impregnation of a FeOx-SiO2 composite, which was synthesized by a sol-gel technique preliminarily, with Rh(NO3)(3) aqueous solution provided better ethanol formation activity than those prepared by co-impregnation and co-sol-gel methods. An ethanol selectivity of 42% was achieved at CO conversion of 12% over a 5 wt% Rh/(5 wt% FeOx-SiO2) catalyst prepared by this method. Larger interfaces between Rh and FeOx species were proposed to be a crucial factor for obtaining higher ethanol selectivity. The co-existence of Rh3+ with Rh-0 and the size of Rh particles also played key roles in ethanol formation. (C) 2011 Elsevier B.V. All rights reserved.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61936]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Wang, Jingjuan,Zhang, Qinghong,Wang, Ye,et al. Rh-catalyzed syngas conversion to ethanol: Studies on the promoting effect of FeOx[J]. http://dx.doi.org/10.1016/j.cattod.2011.03.023,2011.
APA	Wang, Jingjuan,Zhang, Qinghong,Wang, Ye,&张庆红.(2011).Rh-catalyzed syngas conversion to ethanol: Studies on the promoting effect of FeOx.http://dx.doi.org/10.1016/j.cattod.2011.03.023.
MLA	Wang, Jingjuan,et al."Rh-catalyzed syngas conversion to ethanol: Studies on the promoting effect of FeOx".http://dx.doi.org/10.1016/j.cattod.2011.03.023 (2011).