Platinum nanoflowers supported on graphene oxide nanosheets: their green synthesis, growth mechanism, and advanced electrocatalytic properties for methanol oxidation

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	Platinum nanoflowers supported on graphene oxide nanosheets: their green synthesis, growth mechanism, and advanced electrocatalytic properties for methanol oxidation
	Chen, Xiaomei ; Su, Bingyuan ; Wu, Genghuang ; Yang, Chaoyong James ; Zhuang, Zhixia ; Wang, Xiaoru ; Chen, Xi ; Zhuang ZS(庄峙厦)
刊名	http://dx.doi.org/10.1039/c2jm31133j
	2012
关键词	FUNCTIONAL CARBON NANOTUBES CATALYTIC PERFORMANCE FACILE SYNTHESIS FUEL-CELLS NANOPARTICLES NANOSTRUCTURES ELECTROOXIDATION PD NANOCRYSTALS REDUCTION
英文摘要	National Basic Research Program of China [2010CB732402]; National Natural Science Foundation of China [21175112, 20975085]; NFFTBS [J1030415]; This paper reports a nontoxic, rapid, one-pot and template-free synthesis of three-dimensional (3D) Pt nanoflowers (PtNFs) with high yield and good size monodispersity supported on graphene oxide (GO) nanosheets. The key synthesis strategy employed a low-cost, green solvent, ethanol as the reductant and an advanced, powerful 2D carbon material, GO nanosheets as the stabilizing material. The resulting PtNFs-GO nanosheets were characterized by transmission electron microscopy (TEM), high-resolution TEM, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and electrochemical techniques. It was found that the monodispersed, porous PtNFs supported on GO nanosheets were a uniform size of 30 nm and each was composed of numerous "clean'' and small (4 nm) Pt nanoparticles, which revealed an unusually high activity for methanol oxidation reaction compared to commercial Pt black. Furthermore, based on a systematic study of the PtNFs growth conditions, a possible mechanism, and especially the importance of GO in the formation was proposed. Our study demonstrates that GO is a promising support material for developing next-generation advanced Pt based fuel cells and their relevant electrodes in the field of energy.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61795]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Chen, Xiaomei,Su, Bingyuan,Wu, Genghuang,et al. Platinum nanoflowers supported on graphene oxide nanosheets: their green synthesis, growth mechanism, and advanced electrocatalytic properties for methanol oxidation[J]. http://dx.doi.org/10.1039/c2jm31133j,2012.
APA	Chen, Xiaomei.,Su, Bingyuan.,Wu, Genghuang.,Yang, Chaoyong James.,Zhuang, Zhixia.,...&庄峙厦.(2012).Platinum nanoflowers supported on graphene oxide nanosheets: their green synthesis, growth mechanism, and advanced electrocatalytic properties for methanol oxidation.http://dx.doi.org/10.1039/c2jm31133j.
MLA	Chen, Xiaomei,et al."Platinum nanoflowers supported on graphene oxide nanosheets: their green synthesis, growth mechanism, and advanced electrocatalytic properties for methanol oxidation".http://dx.doi.org/10.1039/c2jm31133j (2012).