A DYNAMIC INVESTIGATION OF THE DISSOCIATIVE ADSORPTION OF HCOOH ON Pt(100) SINGLE CRYSTAL ELECTRODE; 甲酸在Pt(100)单晶电极表面解离吸附过程的动力学 | |
Sun, S. G. ; Wang, J. J. ; Mu, J. Q. ; Sun SG(孙世刚) | |
1992 | |
关键词 | Platinum single crystal electrode Formic acid Dissociative adsorption Potential step method |
英文摘要 | Dissociative adsorption of small organic molecules on electrocatalyst is so important molecular process of surcace, which includes stages of adsorption, chemical bond broken and new adsorbate formation. The dynamic study on this reaction will contribute to reveal the origin of interaction between electrode surface and reactants, and to develop and earlab theories of electrocatalysis. In the present work, in situ FTIR studies demonstrated that the dissociative produces of HCOOH on P(1) electrode are CO(ad) species. The oxidation of CO(ad) formed from HCOOH dissociative adsorption on Pt(100) electrode was need as probe reaction, and dynamic properties of ibis dissociative adsorption were investigated by a computerised experimental set-up developed recently in our group. From the analysis of current transtients the rate of dissociative adsorption of HCOOH on Pt(100) electrode has been evaluated under specified conditions. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/61772] |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Sun, S. G.,Wang, J. J.,Mu, J. Q.,et al. A DYNAMIC INVESTIGATION OF THE DISSOCIATIVE ADSORPTION OF HCOOH ON Pt(100) SINGLE CRYSTAL ELECTRODE, 甲酸在Pt(100)单晶电极表面解离吸附过程的动力学[J],1992. |
APA | Sun, S. G.,Wang, J. J.,Mu, J. Q.,&孙世刚.(1992).A DYNAMIC INVESTIGATION OF THE DISSOCIATIVE ADSORPTION OF HCOOH ON Pt(100) SINGLE CRYSTAL ELECTRODE.. |
MLA | Sun, S. G.,et al."A DYNAMIC INVESTIGATION OF THE DISSOCIATIVE ADSORPTION OF HCOOH ON Pt(100) SINGLE CRYSTAL ELECTRODE".(1992). |
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