A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of [Co-3(C4H4O4)(25)(OH)](n)center dot 05nH(2)O

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	A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of [Co-3(C4H4O4)(25)(OH)](n)center dot 05nH(2)O
	Zheng,LS ; Chen,XM ; Huang,RB ; Long,LS ; Ren,YP ; Tong,ML ; Sun,ZG ; Ren YP(任艳平)
刊名	http://dx.doi.org/10.1039/b105482c
	2001-10-07
关键词	COUPLED OXIDATION CARBOXYLATE CHANNELS DESIGN OCTAETHYLPORPHYRIN CHEMISTRY COMPLEXES
英文摘要	A three-dimensional open-framework with unprecedented alternate hexa- and penta-coordinate cobalt(a) sites was obtained from the hydrothermal reaction of cobalt nitrate and succinate in a basic solution. Of the four crystallographically independent Co(a) atoms in the crystal structure of this compound, three are hexa-coordinated and one penta-coordinated. The cobalt(II) atoms are linked by edge-sharing CoOn (n = 5 or 6) polyhedrons. The temperature dependence of the magnetic susceptibility of this compound shows strong antiferromagnetic interaction between the metal atoms.
语种	英语
内容类型	期刊论文
源URL	[http://dspace.xmu.edu.cn/handle/2288/61264]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Zheng,LS,Chen,XM,Huang,RB,et al. A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of [Co-3(C4H4O4)(25)(OH)](n)center dot 05nH(2)O[J]. http://dx.doi.org/10.1039/b105482c,2001.
APA	Zheng,LS.,Chen,XM.,Huang,RB.,Long,LS.,Ren,YP.,...&任艳平.(2001).A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of [Co-3(C4H4O4)(25)(OH)](n)center dot 05nH(2)O.http://dx.doi.org/10.1039/b105482c.
MLA	Zheng,LS,et al."A unique open inorganic-organic framework with alternate hexa- and penta-coordinate cobalt(II) sites Synthesis, crystal structure and magnetic properties of [Co-3(C4H4O4)(25)(OH)](n)center dot 05nH(2)O".http://dx.doi.org/10.1039/b105482c (2001).