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OXIDATIVE COUPLING OF METHANE OVER LAF3/LA2O3 CATALYSTS
Au, C. T. ; Zhang, Y. Q. ; Ng, C. F. ; Wan, H. L. ; Wan HL(万惠霖)
刊名http://dx.doi.org/10.1007/BF00811372
1994
关键词LANTHANUM OXIDE DIMERIZATION HYDROCARBONS CONVERSION
英文摘要We studied the oxidative coupling of methane over the LaF3/La2O3 (50 : 50) catalyst. The catalyst was found active even at 873 K. At 1023 K, the C2 yield was 12.7% at 26.0% CH4 conversion and 49.1% C2 selectivity. It was found to be stable and had a lifetime not less than 50 h at 1023 K. The catalyst was effective in C2H6 conversion to C2H4. XRD results indicated that the catalyst was mainly rhombohedral LaOF. It is suggested that the catalyst has ample stoichiometric defects and generates active oxygen sites suitable for methane dehydrogenation.
语种英语
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/61042]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Au, C. T.,Zhang, Y. Q.,Ng, C. F.,et al. OXIDATIVE COUPLING OF METHANE OVER LAF3/LA2O3 CATALYSTS[J]. http://dx.doi.org/10.1007/BF00811372,1994.
APA Au, C. T.,Zhang, Y. Q.,Ng, C. F.,Wan, H. L.,&万惠霖.(1994).OXIDATIVE COUPLING OF METHANE OVER LAF3/LA2O3 CATALYSTS.http://dx.doi.org/10.1007/BF00811372.
MLA Au, C. T.,et al."OXIDATIVE COUPLING OF METHANE OVER LAF3/LA2O3 CATALYSTS".http://dx.doi.org/10.1007/BF00811372 (1994).
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