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A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye
Zhan, XQ ; Li, DH ; Zheng, H ; Xu, JG ; Xu JG(许金钩)
2007-02-02
关键词nitrite nitrate tetra-substituted amino aluminum phthalocyanine seawater
英文摘要A novel method for the determination of dissolved inorganic nitrite and nitrate in surface seawater was reported, which is based on the diazotization reaction between nitrite and a novel red-region fluorescent dye, tetra-substituted amino aluminum phthalocyanine (TAAlPc). Nitrate is determined as nitrite after reduction on a cadmium column. Under optimal conditions, the linear range of the calibration curve is 21-840 nM for nitrite. The detection limit is 7 nM for and the relative standard deviation for six replicate measurements of a 350 nM nitrite solution is 3.2%. Since the method employs a red-region fluorescent dye (lambda (ex/em) = 610 nm/678 nm), the potential fluorescent background resulting from the organic matters in seawater can be eliminated and thus the sensitivity of the method can be enhanced.
语种英语
出版者MARCEL DEKKER INC
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/12508]  
专题化学化工-已发表论文
推荐引用方式
GB/T 7714
Zhan, XQ,Li, DH,Zheng, H,et al. A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye[J],2007.
APA Zhan, XQ,Li, DH,Zheng, H,Xu, JG,&许金钩.(2007).A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye..
MLA Zhan, XQ,et al."A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye".(2007).
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