A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye | |
Zhan, XQ ; Li, DH ; Zheng, H ; Xu, JG ; Xu JG(许金钩) | |
2007-02-02 | |
关键词 | nitrite nitrate tetra-substituted amino aluminum phthalocyanine seawater |
英文摘要 | A novel method for the determination of dissolved inorganic nitrite and nitrate in surface seawater was reported, which is based on the diazotization reaction between nitrite and a novel red-region fluorescent dye, tetra-substituted amino aluminum phthalocyanine (TAAlPc). Nitrate is determined as nitrite after reduction on a cadmium column. Under optimal conditions, the linear range of the calibration curve is 21-840 nM for nitrite. The detection limit is 7 nM for and the relative standard deviation for six replicate measurements of a 350 nM nitrite solution is 3.2%. Since the method employs a red-region fluorescent dye (lambda (ex/em) = 610 nm/678 nm), the potential fluorescent background resulting from the organic matters in seawater can be eliminated and thus the sensitivity of the method can be enhanced. |
语种 | 英语 |
出版者 | MARCEL DEKKER INC |
内容类型 | 期刊论文 |
源URL | [http://dspace.xmu.edu.cn/handle/2288/12508] ![]() |
专题 | 化学化工-已发表论文 |
推荐引用方式 GB/T 7714 | Zhan, XQ,Li, DH,Zheng, H,et al. A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye[J],2007. |
APA | Zhan, XQ,Li, DH,Zheng, H,Xu, JG,&许金钩.(2007).A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye.. |
MLA | Zhan, XQ,et al."A sensitive fluorimetric method for the determination of nitrite and nitrate in seawater by a novel red-region fluorescence dye".(2007). |
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