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	A new method for the construction of the hydroxylated tropane skeleton: enantioselective synthesis of (-)-Bao Gong Teng A
	Lin, Geng-Jie ; Zheng, Xiao ; Huang, Pei-Qiang ; Huang PQ(黄培强)
	2011-11-25
英文摘要	An efficient and highly diastereoselective method for the construction of the hydroxylated tropane skeleton is described. The method features a new intramolecular reductive coupling reaction of N-acyl N,O-acetal with aldehyde, cooperatively mediated by BF(3)center dot OEt(2) and SmI(2). On the basis of this method, a new enantioselective total synthesis of (-)-Bao Gong Teng A has been accomplished.; NSF of China[20832005, 21072160]; National Basic Research Program (973 Program) of China[2010CB833200]
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://dx.doi.org/doi:10.1039/c0cc04371k]
专题	化学化工－已发表论文
推荐引用方式 GB/T 7714	Lin, Geng-Jie,Zheng, Xiao,Huang, Pei-Qiang,et al. A new method for the construction of the hydroxylated tropane skeleton: enantioselective synthesis of (-)-Bao Gong Teng A[J],2011.
APA	Lin, Geng-Jie,Zheng, Xiao,Huang, Pei-Qiang,&黄培强.(2011).A new method for the construction of the hydroxylated tropane skeleton: enantioselective synthesis of (-)-Bao Gong Teng A..
MLA	Lin, Geng-Jie,et al."A new method for the construction of the hydroxylated tropane skeleton: enantioselective synthesis of (-)-Bao Gong Teng A".(2011).

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