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Parallel Factor Analysis for Excitation Emission Matrix Fluorescence Spectroscopy of Dissolved Organic Matter from a Reservoir-Type River
Guo, W. D. ; Yang, L. Y. ; Wang, F. L. ; Chen, W. Z. ; Wang, X. H. ; Hong, H. S. ; Hong HS(洪华生)
刊名http://dx.doi.org/10.3964/j.issn.1000-0593(2011)02-0427-04
2011-02
关键词DOM ENVIRONMENTS POLLUTION PARAFAC MARINE CARBON CDOM
英文摘要The fluorescent components and their distribution and variation of dissolved organic matter (DOM) were examined using excitation emission matrix fluorescence spectroscopy-parallel factor analysis technique (EEMs-PARAFAC) for samples collected during June, 2008 from Minjiang River, a typical subtropical reservoir-type river ecosystem Three separate fluorescent components were identified by PARAFAC, including two dominant humic-like components (Cl: <250, 325/424 rim; C2; 270, 395/482 nm) and one protein-like component (C3; <250, 280/358 nm), of which humic-like components were dominant. Fluorescence analysis provided a 'fingerprint' technique to trace the mixing of DOM between three tributaries in the upstream of Minjiang River. The nearly constant concentration and composition in the main stream of Minjiang River reflected the effect of dam construction. Correlation and principal component analysis (PCA) revealed that humic-like components were principally derived from flushing of watershed soils, while protein-like component was formed from in-situ production which could be used as a proxy of the concentration of total dissolved nitrogen (TDN). Multi-linear regression of fluorescent components C2 and C3 can be used to trace the variation of dissolved organic carbon (DOC) concentration. This study demonstrates that Minjiang is a typical subtropical reservoir-type river which still keeps relatively 'unpolluted' aquatic environment.
语种英语
内容类型期刊论文
源URL[http://dspace.xmu.edu.cn/handle/2288/60427]  
专题海洋环境-已发表论文
推荐引用方式
GB/T 7714
Guo, W. D.,Yang, L. Y.,Wang, F. L.,et al. Parallel Factor Analysis for Excitation Emission Matrix Fluorescence Spectroscopy of Dissolved Organic Matter from a Reservoir-Type River[J]. http://dx.doi.org/10.3964/j.issn.1000-0593(2011)02-0427-04,2011.
APA Guo, W. D..,Yang, L. Y..,Wang, F. L..,Chen, W. Z..,Wang, X. H..,...&洪华生.(2011).Parallel Factor Analysis for Excitation Emission Matrix Fluorescence Spectroscopy of Dissolved Organic Matter from a Reservoir-Type River.http://dx.doi.org/10.3964/j.issn.1000-0593(2011)02-0427-04.
MLA Guo, W. D.,et al."Parallel Factor Analysis for Excitation Emission Matrix Fluorescence Spectroscopy of Dissolved Organic Matter from a Reservoir-Type River".http://dx.doi.org/10.3964/j.issn.1000-0593(2011)02-0427-04 (2011).
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