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Ethynylphenyl-Linked Carbazoles as a Single-Emitting Component for White Organic Light-Emitting Diodes
Adhikari, Ravi M. ; Duan, Lian ; Hou, Liudong ; Qiu, Yong ; Neckers, Douglas C. ; Shah, Bipin K.
2010-10-12 ; 2010-10-12
关键词CONJUGATED DENDRIMERS ELECTROLUMINESCENT DIODES PHOTOPHYSICAL PROPERTIES TRANSPORT MATERIALS DEVICE APPLICATIONS BLUE POLYMERS COPOLYMERS EMISSION GREEN Chemistry, Physical Materials Science, Multidisciplinary
中文摘要A comparative photophysical Study of several new dendrimers consisting of the ethynylphenyl core and carbazole dendrons (1-5) is presented. Dilute solutions of 1-5 show intense blue emission in dichloromethane (lambda(max) = 410-438 nm, phi(F) = 0.53-0.91, tau(F) = 2.09-3.91 ns). The solvatochromic and solid-state emission behavior of 1-5 (lambda(max) = 426-443 nm, phi(F) = 0.30-0.90) is discussed. The geometry of 5 allows formation of a strong electromeric state, which was not the case with 1, indicating that the ethynylphenyl group can be used to tune dendrimer electroluminescence (EL) properties. An organic light-emitting diode (OLED) consisting of I as the emitting layer showed blue emission (CIE: 0.28, 0.20), whereas the EL of 5 (CIE: 0.34, 0.36) was found to be close to ideal white light. White OLEDs consisting of 5 as the emitting layer showed a maximum brightness of 450 cd/m(2) and a maximum efficiency of 0.11 cd/A at 11 V.
语种英语 ; 英语
出版者AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/81114]  
专题清华大学
推荐引用方式
GB/T 7714
Adhikari, Ravi M.,Duan, Lian,Hou, Liudong,et al. Ethynylphenyl-Linked Carbazoles as a Single-Emitting Component for White Organic Light-Emitting Diodes[J],2010, 2010.
APA Adhikari, Ravi M.,Duan, Lian,Hou, Liudong,Qiu, Yong,Neckers, Douglas C.,&Shah, Bipin K..(2010).Ethynylphenyl-Linked Carbazoles as a Single-Emitting Component for White Organic Light-Emitting Diodes..
MLA Adhikari, Ravi M.,et al."Ethynylphenyl-Linked Carbazoles as a Single-Emitting Component for White Organic Light-Emitting Diodes".(2010).
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