| Synthetic, Structural, Spectroscopic, Electrochemical Studies and Self-assembly of Nanoscale Polyoxometalate-Organic Hybrid Molecular Dumbbells | |
| Zhu, Yi ; Wang, Longsheng ; Hao, Jian ; Xiao, Zicheng ; Wei, Yongge ; Wang, Yuan | |
| 2010-10-12 ; 2010-10-12 | |
| 关键词 | ORGANOIMIDO DERIVATIVES INORGANIC NANOCOMPOSITES OPTICAL-PROPERTIES NMR-SPECTROSCOPY BUILDING-BLOCKS HEXAMOLYBDATE COMPLEXES CLUSTERS ANIONS FUNCTIONALIZATION Chemistry, Multidisciplinary Crystallography Materials Science, Multidisciplinary |
| 中文摘要 | Three rigid-rod conjugated organic-inorganic hybrid nanodumbbells (Bu4N)(4)[O18Mo6N(C6H4)NMo6O18] (1), (Bu4N)(4)[O18Mo6N(C12H8)NMo6O18] (2), and (Bu4N)(4)[O18Mo6N(C14H12)NMo6O18] (3) bearing terminal polyoxometalate (POM) cages, with different lengths Of approximately 2-3 nm and different substituents on the rod, have been synthesized via one-pot reaction of octamolybdate and the appropriate aromatic diamine dihydrochloride with N,N'-dicyclohexylcarbodiimide (DCC) as a dehydrating agent. These complexes have been characterized with UV-vis, IR, H-1 NMR, ESI mass spectrometry. cyclic voltammetry, differential pulse voltammetry, and X-ray single-crystal diffraction techniques. The influence of the rod length and substituents on properties of these complexes has been investigated. In addition, the self-assembly of these nanorods has also been explored. |
| 语种 | 英语 ; 英语 |
| 出版者 | AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| 内容类型 | 期刊论文 |
| 源URL | [http://hdl.handle.net/123456789/81031]  |
| 专题 | 清华大学 |
| 推荐引用方式 GB/T 7714 | Zhu, Yi,Wang, Longsheng,Hao, Jian,et al. Synthetic, Structural, Spectroscopic, Electrochemical Studies and Self-assembly of Nanoscale Polyoxometalate-Organic Hybrid Molecular Dumbbells[J],2010, 2010. |
| APA | Zhu, Yi,Wang, Longsheng,Hao, Jian,Xiao, Zicheng,Wei, Yongge,&Wang, Yuan.(2010).Synthetic, Structural, Spectroscopic, Electrochemical Studies and Self-assembly of Nanoscale Polyoxometalate-Organic Hybrid Molecular Dumbbells.. |
| MLA | Zhu, Yi,et al."Synthetic, Structural, Spectroscopic, Electrochemical Studies and Self-assembly of Nanoscale Polyoxometalate-Organic Hybrid Molecular Dumbbells".(2010). |
| 个性服务 |
| 查看访问统计 |
| 相关权益政策 |
| 暂无数据 |
| 收藏/分享 |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论