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Synthesis and surface modification of tin-copper alloy anode for lithium ion battery by electrodeposition process
Ren Jianguo ; Pu Weihua ; He Xiangming ; Wan Chunrong ; Jiang Changyin
2010-05-10 ; 2010-05-10
关键词lithium ion battery tin-copper alloy heat treatment surface modification THIN-FILM SN PERFORMANCE Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering
中文摘要A pulsed electrodeposition and heat-treatment process was used to prepare copper-tin alloys for the anode of lithium ion battery. The copper-tin alloy electrodes with the structures of sn/Cu6Sn5/Cu3Sn and Sn/Cu3Sn were obtained by plating tin on a substrate of copper foil followed by an anneal-treatment process at 200 degrees C and 300 degrees C. The surface modification of copper-tin alloy electrode was tried. The improved cycle performances and the relatively low specific capacity are due to the formation of copper-tin alloy phases. The main component of the electrode surface changed from Sn/Cu6Sn5 to Cu/Cu6Sn5 after copper coating followed by heat-treatment. After surface modification, the copper-tin alloy electrode presented a high structure stability in a long cycle term. As a result, the copper-tin alloy anode was obtained with high activity and high stability.
语种中文 ; 中文
出版者NORTHWEST INST NONFERROUS METAL RESEARCH ; SHAANXI ; C/O RARE METAL MATERIAL ENGINEERING PRESS, PO BOX 51, XIAN, SHAANXI 710016, PEOPLES R CHINA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/22997]  
专题清华大学
推荐引用方式
GB/T 7714
Ren Jianguo,Pu Weihua,He Xiangming,et al. Synthesis and surface modification of tin-copper alloy anode for lithium ion battery by electrodeposition process[J],2010, 2010.
APA Ren Jianguo,Pu Weihua,He Xiangming,Wan Chunrong,&Jiang Changyin.(2010).Synthesis and surface modification of tin-copper alloy anode for lithium ion battery by electrodeposition process..
MLA Ren Jianguo,et al."Synthesis and surface modification of tin-copper alloy anode for lithium ion battery by electrodeposition process".(2010).
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