Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process | |
Luo Shao-hua ; Tang Zi-long ; Lu Jun-biao ; Zhang Zhong-tai | |
2010-05-10 ; 2010-05-10 | |
关键词 | Experimental Practical/ carbon composite materials iron compounds lithium compounds materials preparation nanoparticles pyrolysis secondary cells/ composite cathode material preparation granulating process microstructure nanoparticles aggregate pyrolysis process carbon source polyvinyl alcohol PVA charge rate discharge rate polarization effect lithium-ion battery LiFePO/sub 4/-C/ A8120 Other methods of preparation of materials A6480G Microstructure A8230L Decomposition reactions (pyrolysis, dissociation, and group ejection) A8630F Secondary cells A6146 Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials B8410E Secondary cells/ LiFePO4-C/int LiFePO4/int PO4/int Fe/int Li/int O4/int C/int O/int P/int LiFePO4/ss PO4/ss Fe/ss Li/ss O4/ss O/ss P/ss C/el |
中文摘要 | LiFePO/sub 4//carbon composite cathode material with the microstructure of nano-particles aggregated was prepared by granulating and subsequent pyrolysis process with carbon source of polyvinyl alcohol (PVA). The single LiFePO/sub 4/ phase and amorphous carbon could be found in the products. The influence of granulating process on the microstructure was significant. A special micro-morphology of optimum sample was observed. The capacity and cycle performance were studied at the charge and discharge rate of 0.1 C,0.2 C,0.5 C and 1 C. The optimum cathode sample (LFP/C4) has high reversible capacity and well cycle stability. Along with the increasing of cycle number, the capacity increases to its saturate value. After several cycles, the capacity is 149.9, 136.9, 123.2, 108.1 mAh middot g/sup -1/, respectively. Specially, at high 1 C rate, the cell reaches 63.6% of theory capacity to discharge capacity and has minor polarization effect with only 177 mV of potential difference ( Delta V) of charge-discharge median capacity. |
语种 | 中文 ; 中文 |
出版者 | Tianjin Inst. Power Sources ; China |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/20864] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Luo Shao-hua,Tang Zi-long,Lu Jun-biao,et al. Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process[J],2010, 2010. |
APA | Luo Shao-hua,Tang Zi-long,Lu Jun-biao,&Zhang Zhong-tai.(2010).Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process.. |
MLA | Luo Shao-hua,et al."Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process".(2010). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论