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Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process
Luo Shao-hua ; Tang Zi-long ; Lu Jun-biao ; Zhang Zhong-tai
2010-05-10 ; 2010-05-10
关键词Experimental Practical/ carbon composite materials iron compounds lithium compounds materials preparation nanoparticles pyrolysis secondary cells/ composite cathode material preparation granulating process microstructure nanoparticles aggregate pyrolysis process carbon source polyvinyl alcohol PVA charge rate discharge rate polarization effect lithium-ion battery LiFePO/sub 4/-C/ A8120 Other methods of preparation of materials A6480G Microstructure A8230L Decomposition reactions (pyrolysis, dissociation, and group ejection) A8630F Secondary cells A6146 Structure of solid clusters, nanoparticles, nanotubes and nanostructured materials B8410E Secondary cells/ LiFePO4-C/int LiFePO4/int PO4/int Fe/int Li/int O4/int C/int O/int P/int LiFePO4/ss PO4/ss Fe/ss Li/ss O4/ss O/ss P/ss C/el
中文摘要LiFePO/sub 4//carbon composite cathode material with the microstructure of nano-particles aggregated was prepared by granulating and subsequent pyrolysis process with carbon source of polyvinyl alcohol (PVA). The single LiFePO/sub 4/ phase and amorphous carbon could be found in the products. The influence of granulating process on the microstructure was significant. A special micro-morphology of optimum sample was observed. The capacity and cycle performance were studied at the charge and discharge rate of 0.1 C,0.2 C,0.5 C and 1 C. The optimum cathode sample (LFP/C4) has high reversible capacity and well cycle stability. Along with the increasing of cycle number, the capacity increases to its saturate value. After several cycles, the capacity is 149.9, 136.9, 123.2, 108.1 mAh middot g/sup -1/, respectively. Specially, at high 1 C rate, the cell reaches 63.6% of theory capacity to discharge capacity and has minor polarization effect with only 177 mV of potential difference ( Delta V) of charge-discharge median capacity.
语种中文 ; 中文
出版者Tianjin Inst. Power Sources ; China
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/20864]  
专题清华大学
推荐引用方式
GB/T 7714
Luo Shao-hua,Tang Zi-long,Lu Jun-biao,et al. Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process[J],2010, 2010.
APA Luo Shao-hua,Tang Zi-long,Lu Jun-biao,&Zhang Zhong-tai.(2010).Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process..
MLA Luo Shao-hua,et al."Synthesis and performance of LiFePO/sub 4//C composite cathode material prepared by granulating process".(2010).
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