Photoluminescence properties of Zn2SiO4 : Mn2+ inverse opals | |
Li, B ; Zhou, J ; Zong, RL ; Li, LT | |
2010-05-10 ; 2010-05-10 | |
会议名称 | HIGH-PERFORMANCE CERAMICS III, PTS 1 AND 2 ; 3rd China International Conference on High-Performance Ceramics (CICC-3) ; Shenzhen, PEOPLES R CHINA ; Web of Science |
关键词 | inverse opals photoluminescence Zn2SiO4 : Mn2+ OXIDIZED POROUS SILICON ZINC SILICATE LAYERS PARTICLES Materials Science, Ceramics Materials Science, Composites |
中文摘要 | Mn2+-doped Zn2SiO4 inverse opals were synthesized by sol-gel technique combined with the self-assembly of the opal template. Zn2SiO4:Mn2+ precursors were infiltrated into the interstices of the opal template assembled by polystyrene spheres. The polystyrene template was removed by calcining and nanocrystals of Mn2+-doped Zn2SiO4 were obtained in the void of opal template. The inverse opals show photonic crystal behavior and emit yellow light initially with the luminescent peak at 562 nm corresponding with the fact that beta-phase is the dominant phase for nanocrystals less than 30nm. As the beta-phase transformed to a-phase with the gradual increase of treating temperature and the growth of the crystal, the luminescence from Zn2SiO4:Mn2+ phosphors change from yellow to green. |
会议录出版者 | TRANS TECH PUBLICATIONS LTD ; ZURICH-UETIKON ; BRANDRAIN 6, CH-8707 ZURICH-UETIKON, SWITZERLAND |
语种 | 英语 ; 英语 |
内容类型 | 会议论文 |
源URL | [http://hdl.handle.net/123456789/18074] ![]() |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Li, B,Zhou, J,Zong, RL,et al. Photoluminescence properties of Zn2SiO4 : Mn2+ inverse opals[C]. 见:HIGH-PERFORMANCE CERAMICS III, PTS 1 AND 2, 3rd China International Conference on High-Performance Ceramics (CICC-3), Shenzhen, PEOPLES R CHINA, Web of Science. |
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