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Monodispersed microcapsules enclosing ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate
Yang, W. W. ; Lu, Y. C. ; Xiang, Z. Y. ; Luo, G. S.
2010-05-07 ; 2010-05-07
关键词ionic liquid microcapsules microfluidic approach POLYSTYRENE MICROCAPSULES METAL-IONS SEPARATION EXTRACTION IMMOBILIZATION ALIQUAT-336 STABILITY MEMBRANES SOLVENTS CATALYST Chemistry, Applied Engineering, Chemical Polymer Science
中文摘要The widespread research of ionic liquids is mainly because of their unique characteristics, which allow the possibility for more efficient reactions and separations in chemical processes. To achieve a successful commercial status, several problems of ionic liquids should be solved, including loss of ionic liquids and high viscosity that effects on fluid flow and mass transfer. In this study, hollow polysulfone microcapsules filled with ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM]PF6 were prepared via a two-stage microfluidic approach. The results of the preparation showed that [BMIM]PF6 was Successfully encapsulated with polysulfone, as an encapsulation capacity of 30.8% was achieved. Smaller microcapsules were produced with smaller size of nozzle, lower droplet phase flow rate or higher continuous phase flow rate. The microcapsules had excellent monodispersity and spherical morphology with extremely narrow size distribution. Besides, they had good stability of ionic liquid immobilization. The microfluidic approach has been proved successful to fabricate microcapsules, with advantages of extremely narrow size distribution, easy-controlled operating conditions to obtain different size of microcapsules, possibility for on line observation of preparation process. (c) 2006 Elsevier B.V. All rights reserved.
语种英语 ; 英语
出版者ELSEVIER SCIENCE BV ; AMSTERDAM ; PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/17822]  
专题清华大学
推荐引用方式
GB/T 7714
Yang, W. W.,Lu, Y. C.,Xiang, Z. Y.,et al. Monodispersed microcapsules enclosing ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate[J],2010, 2010.
APA Yang, W. W.,Lu, Y. C.,Xiang, Z. Y.,&Luo, G. S..(2010).Monodispersed microcapsules enclosing ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate..
MLA Yang, W. W.,et al."Monodispersed microcapsules enclosing ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate".(2010).
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