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Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts
Zhang, C ; Zhu, YF
2010-05-06 ; 2010-05-06
关键词AURIVILLIUS PHASE BI2SRTA2O9 SOL-GEL PROCESS AQUEOUS-SOLUTIONS COMPOSITE NANOSTRUCTURES DIELECTRIC-PROPERTIES GOLD NANOPARTICLES PROTONATED FORM RHODAMINE-B OXIDE IRRADIATION Chemistry, Physical Materials Science, Multidisciplinary
中文摘要Square Bi2WO6 nanoplates have been successfully synthesized by simple hydrothermal process. The effects of hydrothermal temperature and reaction time on morphologies and sizes of the nanoplates were investigated. These nanoplates are square geometric shapes having their basal plane as the (001) plane of orthorhombic Bi2WO6. On the basis of results of morphologies observation and selected area electron diffraction of series samples, a possible growth mechanism of the nanoplates is revealed. The square laminar shape could be attributed to anisotropic growth along the (001) plane, which is parallel to their intrinsic layer structure. UV-visible diffuse reflection spectra of the prepared Bi2WO6 nanoplates indicate they had absorption in the visible region, but a blue shift appeared compared to their bulk counterparts. Their photocatalytic activities are determined by rhodamine B degradation under visible light irradiation (lambda > 400 nm). The reaction constant (k) of the best quality Bi2WO6 nanoplates is three times that of the sample prepared by solid-state reaction, which indicates much higher photocatalytic activities of the nanoplates performed under visible light irradiation.
语种英语 ; 英语
出版者AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
内容类型期刊论文
源URL[http://hdl.handle.net/123456789/13340]  
专题清华大学
推荐引用方式
GB/T 7714
Zhang, C,Zhu, YF. Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts[J],2010, 2010.
APA Zhang, C,&Zhu, YF.(2010).Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts..
MLA Zhang, C,et al."Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts".(2010).
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