General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants | |
Liu, Xiaowei ; Zhang, Yongming ; Wang, Long ; Fu, Hua ; Jiang, Yuyang ; Zhao, Yufen | |
2010-05-06 ; 2010-05-06 | |
关键词 | CARBON-HYDROGEN BONDS CHLORAMINE-T NITROGEN ATOM BROMAMINE-T INTRAMOLECULAR AMIDATION NITRENE SOURCE AMINATION AZIRIDINATION FUNCTIONALIZATION ACTIVATION Chemistry, Organic |
中文摘要 | We have developed a general and efficient method for copper-catalyzed amidation of saturated C-H bonds under mild conditions, and the used substrates include benzylic reagents, the N,N-dimethylaniline derivatives, the free carboxamides, and sulfonamides. The protocol uses inexpensive and readily available CuBr/N-halosuccinimide (NBS or NCS) as the catalyst/oxidant, so it provides practical applications for synthesis of various amides via C-H activation. |
语种 | 英语 ; 英语 |
出版者 | AMER CHEMICAL SOC ; WASHINGTON ; 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
内容类型 | 期刊论文 |
源URL | [http://hdl.handle.net/123456789/12454] |
专题 | 清华大学 |
推荐引用方式 GB/T 7714 | Liu, Xiaowei,Zhang, Yongming,Wang, Long,et al. General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants[J],2010, 2010. |
APA | Liu, Xiaowei,Zhang, Yongming,Wang, Long,Fu, Hua,Jiang, Yuyang,&Zhao, Yufen.(2010).General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants.. |
MLA | Liu, Xiaowei,et al."General and efficient copper-catalyzed amidation of saturated C-H bonds using N-halosuccinimides as the oxidants".(2010). |
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