Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones
Shi, Renyi1; Niu, Huiying1; Lu, Lijun1; Lei AW(雷爱文)1,2
刊名Chemical Communications
2017
卷号53期号:11页码:1908-1911
ISSN号1359-7345
通讯作者雷爱文
英文摘要

It is important to achieve diverse functionalization of tertiary anilines due to their importance in biological molecules, pharmaceutical, functional materials, and ligands. A straightforward Pd/Cu-catalyzed oxidative C–H bond activation/N-dealkylative carbonylation of tertiary [1,1′-biphenyl]-2-anilines towards the synthesis of various biologically important phenanthridin-6(5H)-ones has been developed. A wide range of functional groups are well tolerated in this transformation. Moreover, O2 is utilized as the terminal oxidant to promote the oxidative carbonylation process.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (21390400;21520102003;21272180;21302148);the Hubei Province Natural Science Foundation of China (2013CFA081);the Research Fund for the Doctoral Program of Higher Education of China (20120141130002);the Ministry of Science and Technology of China (2012YQ120060);the Program of Introducing Talents of Discipline to Universities of China (111 Program)
语种英语
WOS记录号WOS:000395590800032
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/21525]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Wuhan Univ, Inst Adv Studies, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Shi, Renyi,Niu, Huiying,Lu, Lijun,et al. Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones[J]. Chemical Communications,2017,53(11):1908-1911.
APA Shi, Renyi,Niu, Huiying,Lu, Lijun,&Lei AW.(2017).Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones.Chemical Communications,53(11),1908-1911.
MLA Shi, Renyi,et al."Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones".Chemical Communications 53.11(2017):1908-1911.
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