Enhanced crystallization and stability of perovskites by a cross-linkable fullerene for high-performance solar cells
Li, M; Chao, YH; Kang, T; Wang, ZK; Yang, YG; Feng, SL; Hu, Y; Gao, XY; Liao, LS; Hsu, CS
刊名JOURNAL OF MATERIALS CHEMISTRY A
2016
卷号4期号:39页码:15088-15094
ISSN号2050-7488
通讯作者Wang, ZK ; Liao, LS (reprint author), Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Inst Funct Nano & So Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Jiangsu, Peoples R China. ; Hsu, CS (reprint author), Natl Chiao Tung Univ, Dept Appl Chem, 1001 Ta Hsueh Rd, Hsinchu 30010, Taiwan.
英文摘要Organic-inorganic halide perovskite solar cells (PSCs) still suffer from the issues of poor reproducibility and inferior stability despite their considerable increase in efficiency. Here, we demonstrate planar PSCs with simultaneously improved device characteristics and stability by introducing a cross-linkable [6,6]-phenyl-C-61-butyric styryl dendron ester (PCBSD) into CH3NH3PbIxCl3-x perovskites. The cross-linkable merit of C-PCBSD can enhance the crystallization of perovskites and address the issue of low electron extraction efficiency. In addition, the anti-solvent network of C-PCBSD facilitates the sequential solution process and prevents washing by the solvent used in the upper layer. The C-PCBSD network resisted the moisture incursion and protected the interfaces from erosion, and it passivated the voids or pinholes generated in the bulk active layer. As a result, an outstanding PSC with a power conversion efficiency of 17.21% is achieved with evidently improved cell stability.
收录类别SCI
语种英语
WOS记录号WOS:000386700600026
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/26495]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式
GB/T 7714
Li, M,Chao, YH,Kang, T,et al. Enhanced crystallization and stability of perovskites by a cross-linkable fullerene for high-performance solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(39):15088-15094.
APA Li, M.,Chao, YH.,Kang, T.,Wang, ZK.,Yang, YG.,...&Hsu, CS.(2016).Enhanced crystallization and stability of perovskites by a cross-linkable fullerene for high-performance solar cells.JOURNAL OF MATERIALS CHEMISTRY A,4(39),15088-15094.
MLA Li, M,et al."Enhanced crystallization and stability of perovskites by a cross-linkable fullerene for high-performance solar cells".JOURNAL OF MATERIALS CHEMISTRY A 4.39(2016):15088-15094.
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