A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI
Chen, LH; Zheng, T; Bao, SS; Zhang, LJ; Liu, HK; Zheng, LM; Wang, JQ; Wang, YX; Juan, DW; Chai, ZF
刊名CHEMISTRY-A EUROPEAN JOURNAL
2016
卷号22期号:34页码:11954-11957
关键词magnetism mixed-valent compounds pentavalent uranyl solid-state structure uranium phosphonate
ISSN号0947-6539
通讯作者Juan, DW ; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China. ; Juan, DW ; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China.
英文摘要It is shown that (UO2+)-O-V ions can reside at (UO22+)-O-VI lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U-IV, U-V, and U-VI. The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements.
收录类别SCI
语种英语
WOS记录号WOS:000382925000007
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/26408]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式
GB/T 7714
Chen, LH,Zheng, T,Bao, SS,et al. A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(34):11954-11957.
APA Chen, LH.,Zheng, T.,Bao, SS.,Zhang, LJ.,Liu, HK.,...&Wang, SA.(2016).A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI.CHEMISTRY-A EUROPEAN JOURNAL,22(34),11954-11957.
MLA Chen, LH,et al."A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI".CHEMISTRY-A EUROPEAN JOURNAL 22.34(2016):11954-11957.
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