A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI | |
Chen, LH; Zheng, T; Bao, SS; Zhang, LJ; Liu, HK; Zheng, LM; Wang, JQ; Wang, YX; Juan, DW; Chai, ZF | |
刊名 | CHEMISTRY-A EUROPEAN JOURNAL |
2016 | |
卷号 | 22期号:34页码:11954-11957 |
关键词 | magnetism mixed-valent compounds pentavalent uranyl solid-state structure uranium phosphonate |
ISSN号 | 0947-6539 |
通讯作者 | Juan, DW ; Wang, SA (reprint author), Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China. ; Juan, DW ; Wang, SA (reprint author), Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China. |
英文摘要 | It is shown that (UO2+)-O-V ions can reside at (UO22+)-O-VI lattice sites during mild reduction and crystallization process under solvothermal conditions, yielding a complicated and rare mixed-valent uranium phosphonate compound that simultaneously contains U-IV, U-V, and U-VI. The presence of uranium with three oxidation states was confirmed by various characterization techniques, including X-ray crystallography, X-ray photoelectron, electron paramagnetic resonance, FTIR, UV/Vis-NIR absorption, and synchrotron radiation X-ray absorption spectroscopy, and magnetism measurements. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000382925000007 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/26408] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Chen, LH,Zheng, T,Bao, SS,et al. A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(34):11954-11957. |
APA | Chen, LH.,Zheng, T.,Bao, SS.,Zhang, LJ.,Liu, HK.,...&Wang, SA.(2016).A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI.CHEMISTRY-A EUROPEAN JOURNAL,22(34),11954-11957. |
MLA | Chen, LH,et al."A Mixed-Valent Uranium Phosphonate Framework Containing U-IV, U-V, and U-VI".CHEMISTRY-A EUROPEAN JOURNAL 22.34(2016):11954-11957. |
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