Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups

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	Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups
	Ceng XH(曾祥华)1,2; Xu DQ(徐大乾)1; Miao CX(苗成霞)1 ; Xia CG(夏春谷)1 ; Sun W(孙伟)1
刊名	RSC Advances
	2014
卷号	4 期号:87 页码:46494-46497
ISSN号	2046-2069
通讯作者	孙伟
英文摘要	An efficient method for synthesizing diaryl ketones via merging of oxidative cleavage of C–C double bonds and recombination of aromatic groups is developed with Et₄NI (2.5 mol%) as the catalyst and NaIO₄ as the oxidant. The control experiments provide valuable mechanistic insights into the formation of diaryl ketones, and suggest that NaIO₄ serves as an epoxidation and nucleophilic deformylation reagent.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21103207)
语种	英语
WOS记录号	WOS:000342761800012
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/21324]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
推荐引用方式 GB/T 7714	Ceng XH,Xu DQ,Miao CX,et al. Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups[J]. RSC Advances,2014,4(87):46494-46497.
APA	Ceng XH,Xu DQ,Miao CX,Xia CG,&Sun W.(2014).Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups.RSC Advances,4(87),46494-46497.
MLA	Ceng XH,et al."Tetraethylammonium iodide catalyzed synthesis of diaryl ketones via the merger of cleavage of C-C double bonds and recombination of aromatic groups".RSC Advances 4.87(2014):46494-46497.