Nickel catalyst stabilization via graphene encapsulation for enhanced methanation reaction | |
Wang, Chao1,2; Zhai, Peng1; Zhang, Zhichao3; Zhou, Yi1; Zhang, Jiakang1; Zhang, Hui4; Shi, Zujin1; Han, Ray P. S.2; Huang, Fuqiang1,4; Ma, Ding1 | |
刊名 | JOURNAL OF CATALYSIS |
2016-02-01 | |
卷号 | 334页码:42-51 |
关键词 | Arc discharge Graphene encapsulation Nickel nanoparticles Catalyst stabilization Methanation |
英文摘要 | Synthesis of chemically stable non-precious-metal 3d-block transition metal nanocatalysts for catalytic syngas conversion remains a great challenge, since the nanocatalysts are usually too active to remain stable under ambient conditions. In situ grown (N-doped) graphene-encapsulated Ni nanoparticles (NPs) (Ni@G, Ni@G-N) were successfully obtained by a simple route via an arc-discharge method. The Ni@G composite is composed of a graphene sheath and a metallic nickel core. The carbon layer can prevent the inner Ni NPs from being etched when they are exposed to air, H2O2 or acid. Moreover, the as-prepared Ni@G exhibit excellent catalytic activity and methane selectivity and high stability in the methanation reaction. The catalytic performance can be further improved by doping nitrogen into the graphene shell. This method provides a good procedure for graphene encapsulation of non-precious-metal nanoparticles. (C) 2015 Elsevier Inc. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Physical ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | OXYGEN REDUCTION REACTION ; SYNTHETIC NATURAL-GAS ; CO METHANATION ; CARBON NANOTUBES ; ARC-DISCHARGE ; HIGH-QUALITY ; PERFORMANCE ; NANOPARTICLES ; STORAGE ; GROWTH |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000369458100005 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/23261] |
专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Coll Engn, Beijing 100871, Peoples R China 3.Beijing Univ Chem Technol, Beijing 100029, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Chao,Zhai, Peng,Zhang, Zhichao,et al. Nickel catalyst stabilization via graphene encapsulation for enhanced methanation reaction[J]. JOURNAL OF CATALYSIS,2016,334:42-51. |
APA | Wang, Chao.,Zhai, Peng.,Zhang, Zhichao.,Zhou, Yi.,Zhang, Jiakang.,...&Ma, Ding.(2016).Nickel catalyst stabilization via graphene encapsulation for enhanced methanation reaction.JOURNAL OF CATALYSIS,334,42-51. |
MLA | Wang, Chao,et al."Nickel catalyst stabilization via graphene encapsulation for enhanced methanation reaction".JOURNAL OF CATALYSIS 334(2016):42-51. |
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