Co nanoparticles embedded in a 3D CoO matrix for electrocatalytic hydrogen evolution | |
Liu, Xiangye1,2; Dong, Chenlong1,2; Dong, Wujie1,2; Wang, Xin1,2; Yuan, Xiaotao1,2; Huang, Fuqiang1,2,3,4 | |
刊名 | RSC ADVANCES
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2016 | |
卷号 | 6期号:45页码:38515-38520 |
英文摘要 | Earth-abundant and highly efficient electrocatalysts for the hydrogen evolution reaction (HER) are desired for hydrogen production from water-splitting. Here, Co nanoparticles were embedded in the 3D CoO matrix via a template-free method, including cobalt hydroxy-carbonate nanowire arrays grown on Ni foam and the following non-contact Al-reduction process. The as-prepared 3D hierarchical structured Co/CoO nanowires possess good charge transfer and mass transport properties, and a synergistic effect at the Co/CoO interface can hugely facilitate the HER kinetics. A suitable balance between Co and CoO in the catalyst is crucial for high catalytic activity. And the optimal Co/CoO array exhibited outstanding HER activities in 1 M NaOH, achieving nearly zero onset potential, and a current density of 100 mA cm(-2) with a small overpotential of 167 mV. They also showed good long-term stabilities. This hybrid Co/CoO nanowire array is a promising material for large-scale hydrogen production from water-splitting. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | CORE/SHELL NANOSHEETS ; CATALYTIC-ACTIVITY ; OXYGEN EVOLUTION ; NANOWIRE ARRAYS ; EFFICIENT ; ELECTRODES ; CATHODE ; WATER ; NANOCRYSTALS ; PERFORMANCE |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000374972800003 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/23065] ![]() |
专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Xiangye,Dong, Chenlong,Dong, Wujie,et al. Co nanoparticles embedded in a 3D CoO matrix for electrocatalytic hydrogen evolution[J]. RSC ADVANCES,2016,6(45):38515-38520. |
APA | Liu, Xiangye,Dong, Chenlong,Dong, Wujie,Wang, Xin,Yuan, Xiaotao,&Huang, Fuqiang.(2016).Co nanoparticles embedded in a 3D CoO matrix for electrocatalytic hydrogen evolution.RSC ADVANCES,6(45),38515-38520. |
MLA | Liu, Xiangye,et al."Co nanoparticles embedded in a 3D CoO matrix for electrocatalytic hydrogen evolution".RSC ADVANCES 6.45(2016):38515-38520. |
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