Uptake, translocation and biotransformation kinetics of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.)
Xu, Xuehui; Wen, Bei; Huang, Honglin; Wang, Sen; Han, Ruixia; Zhang, Shuzhen
刊名ENVIRONMENTAL POLLUTION
2016-01
卷号208期号:0页码:714-722
关键词PBDEs OH-PBDEs MeO-PBDEs Biotransformation Maize
英文摘要This study presents a detailed kinetic investigation on the uptake, acropetal translocation and transformation of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.) by hydroponic exposure. Root uptake followed the order: BDE-47 > 6-MeO-BDE-47 > 6-OH-BDE-47, while 6-OH-BDE-47 was the most prone to acropetal translocation. Debromination rates of BDE-47 were 1.31 and 1.46 times greater than the hydroxylation and methoxylation rates, respectively. Transformation from BDE-47 to lower brominated OH/MeO-PBDEs occurred mainly through debromination first followed by hydroxylation or methoxylation. There was no transformation from 6-OH-BDE-47 or 6-MeO-BDE-47 to PBDEs. Methylation rate of 6-OH-BDE-47 was twice as high as that of 6-MeO-BDE-47 hydroxylation, indicating methylation of 6-OH-BDE-47 was easier and more rapid than hydroxylation of 6-MeO-BDE-47. Debromination and isomerization were potential metabolic pathways for 6-OH-BDE-47 and 6-MeO-BDE-47 in maize. This study provides important information for better understanding the mechanism on plant uptake and transformation of PBDEs. (C) 2015 Elsevier Ltd. All rights reserved.
收录类别SCI
内容类型期刊论文
源URL[http://ir.rcees.ac.cn/handle/311016/35978]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
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GB/T 7714
Xu, Xuehui,Wen, Bei,Huang, Honglin,et al. Uptake, translocation and biotransformation kinetics of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.)[J]. ENVIRONMENTAL POLLUTION,2016,208(0):714-722.
APA Xu, Xuehui,Wen, Bei,Huang, Honglin,Wang, Sen,Han, Ruixia,&Zhang, Shuzhen.(2016).Uptake, translocation and biotransformation kinetics of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.).ENVIRONMENTAL POLLUTION,208(0),714-722.
MLA Xu, Xuehui,et al."Uptake, translocation and biotransformation kinetics of BDE-47, 6-OH-BDE-47 and 6-MeO-BDE-47 in maize (Zea mays L.)".ENVIRONMENTAL POLLUTION 208.0(2016):714-722.
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