Hyperjapones F-I, terpenoid polymethylated acylphloroglucinols from Hypericum japonicum

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	Hyperjapones F-I, terpenoid polymethylated acylphloroglucinols from Hypericum japonicum
	Li, Yan-Ping 1,2; Yang, Xing-Wei1,3 ; Xia, Fan 1,3; Yan, Hui 1,3; Ma, Wei-Guang 2; Xu, Gang1,3
刊名	TETRAHEDRON LETTERS
	2016-12-28
卷号	57 期号:52 页码:5868-5871
关键词	Terpenoid Polymethylated acylphloroglucinol Hypericum japonicum Hyperjapones F-I
英文摘要	Hyperjapones F-I (1-4), novel terpenoid polymethylated acylphloroglucinols (TPAPs) with three unusual carbon skeletons, were characterized from Hypericum japonicum. Their structures were determined on the basis of comprehensive MS and NMR spectroscopic data. Compounds 1 and 2 could be formed by hybridization of a trimethylated acylphloroglucinol core with a sabinene-type monoterpenoid unit, while compounds 3 and 4 contained a pinene-type monoterpenoid unit in their molecules. Biosynthetically, a key hetero-Diels-Alder mechanism was proposed for the generation of compounds 1-4. (C) 2016 Elsevier Ltd. All rights reserved.
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	POLYCYCLIC POLYPRENYLATED ACYLPHLOROGLUCINOL ; PHLOROGLUCINOL DERIVATIVES ; BIOMIMETIC SYNTHESIS ; PSIDIUM-GUAJAVA ; A-E ; MEROTERPENOIDS ; SKELETON ; HENRYI ; LEAVES ; CORES
收录类别	SCI
语种	英语
WOS记录号	WOS:000390738700008
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/33798]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Yunnan Univ Tradit Chinese Med, Res Ctr Biotransformat Med Plants, Kunming 650500, Peoples R China 3.Yunnan Key Lab Nat Med Chem, Kunming 650201, Peoples R China
推荐引用方式 GB/T 7714	Li, Yan-Ping,Yang, Xing-Wei,Xia, Fan,et al. Hyperjapones F-I, terpenoid polymethylated acylphloroglucinols from Hypericum japonicum[J]. TETRAHEDRON LETTERS,2016,57(52):5868-5871.
APA	Li, Yan-Ping,Yang, Xing-Wei,Xia, Fan,Yan, Hui,Ma, Wei-Guang,&Xu, Gang.(2016).Hyperjapones F-I, terpenoid polymethylated acylphloroglucinols from Hypericum japonicum.TETRAHEDRON LETTERS,57(52),5868-5871.
MLA	Li, Yan-Ping,et al."Hyperjapones F-I, terpenoid polymethylated acylphloroglucinols from Hypericum japonicum".TETRAHEDRON LETTERS 57.52(2016):5868-5871.