Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries | |
Xu YiTao; Guo Ying; Li Chang; Zhou XuanYu; Tucker Michael C.; Fu XianZhu; Sun Rong; Wong ChingPing | |
刊名 | NANO ENERGY |
2015 | |
英文摘要 | Cu2O microspheres were successfully encapsulated by graphene oxide (GO) nano-sheets and used directly as the anode material for lithium ion batteries. The core-shell structured Cu2O@GO composite delivered a reversible capacity of 458 mA h g(-1) at a current density of 100 mA g(-1) after 50 cycles. Even at a high charge-discharge rate of 1000 mA g(-1), Cu2O@GO still demonstrated a reversible capacity of 240 mA h g(-1) after 200 cycles, significantly higher than those of the bare Cu2O microspheres (37 mA h g(-1)) and GO nano-sheets (11 mA h g(-1)). The rate capability evaluated by the ratio of capacity at 100 mA g(-1)/1000 mA g(-1) current density was 49%, 25% and 9.8% for Cu2O@GO, bare Cu2O and GO, respectively. The greatly enhanced performance for GO nano-sheets wrapped Cu2O microspheres composite mainly resulted from the synergistic effect of Cu2O microspheres and GO nano-sheets core-shell composite: the flexible in-situ electrochemically reduced GO nano-sheet coating layer functioning as an efficient three dimensional (3D) conductive network and lithium storage active material; the Cu2O microsphere core functioning as a skeleton to support multilayer GO sheets and avoid GO nano-sheets aggregation. (C) 2014 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
原文出处 | http://www.sciencedirect.com/science/article/pii/S2211285514200395 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.siat.ac.cn:8080/handle/172644/6637] |
专题 | 深圳先进技术研究院_集成所 |
作者单位 | NANO ENERGY |
推荐引用方式 GB/T 7714 | Xu YiTao,Guo Ying,Li Chang,et al. Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries[J]. NANO ENERGY,2015. |
APA | Xu YiTao.,Guo Ying.,Li Chang.,Zhou XuanYu.,Tucker Michael C..,...&Wong ChingPing.(2015).Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries.NANO ENERGY. |
MLA | Xu YiTao,et al."Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries".NANO ENERGY (2015). |
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