Ultratrace Determination of Tin, Germanium, and Selenium by Hydride Generation Coupled with a Novel Solution-Cathode Glow Discharge-Atomic Emission Spectrometry Method

CORC > 上海硅酸盐研究所 > 中国科学院上海硅酸盐研究所 > 结构陶瓷与复合材料工程研究中心 > 期刊论文

	Ultratrace Determination of Tin, Germanium, and Selenium by Hydride Generation Coupled with a Novel Solution-Cathode Glow Discharge-Atomic Emission Spectrometry Method
	Huang, Chuchu; Li, Qing; Mo, Jiamei; Wang, Zheng
刊名	ANALYTICAL CHEMISTRY
	2016-12-06
卷号	88 期号:23 页码:11559-11567
英文摘要	We herein describe a novel method of hydride generation (HG) coupled to a newly designed atmospheric pressure solution-cathode glow discharge (SCGD) spectrometric technique for the ultratrace determination of tin, germanium, and selenium. In this novel SCGD process, gas introduction was permitted using a hollow titanium tube as both the anode and sampling port. In these experiments, the analytes were converted into volatile hydrides upon passing through the hydride generator, and were introduced into the near-anode region of the SCGD system, where they were detected directly by atomic emission spectrometry (AES). A significant improvement in both selectivity and sensitivity was achieved, which was reflected in an improvement in the detection limits (DLs) by 3 orders of magnitude, in addition to successful valence analysis of Se without the requirement for chromatographic separation. In the absence of a strict sample pretreatment process and with a reduction in electrolyte consumption, the detection limits of Sn, Ge, and Se were determined to be 0.8, 0.5, and 0.2 mu g.L-1. Moreover, our HG-SCGD-AES system demonstrated excellent repeatability (<3% peak height relative standard deviation) and more than 2 orders of linear dynamic range. The optimal operating conditions are outlined herein, and the analytical performance of the system is evaluated as described. Furthermore, our method was applied for the analysis of Sn, Ge, and Se in both environmental and biological samples, and the obtained results were in good agreement with reference values.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Analytical
研究领域[WOS]	Chemistry
关键词[WOS]	DIELECTRIC-BARRIER DISCHARGE ; ABSORPTION-SPECTROMETRY ; FLUORESCENCE SPECTROMETRY ; LIQUID CATHODE ; ANALYTICAL PERFORMANCE ; SPECIATION ANALYSIS ; SIGNAL ENHANCEMENT ; ANTIMONY ; SAMPLES ; CONTACT
收录类别	SCI
语种	英语
WOS记录号	WOS:000389556900045
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/21940]
专题	上海硅酸盐研究所_结构陶瓷与复合材料工程研究中心_期刊论文
作者单位	Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
推荐引用方式 GB/T 7714	Huang, Chuchu,Li, Qing,Mo, Jiamei,et al. Ultratrace Determination of Tin, Germanium, and Selenium by Hydride Generation Coupled with a Novel Solution-Cathode Glow Discharge-Atomic Emission Spectrometry Method[J]. ANALYTICAL CHEMISTRY,2016,88(23):11559-11567.
APA	Huang, Chuchu,Li, Qing,Mo, Jiamei,&Wang, Zheng.(2016).Ultratrace Determination of Tin, Germanium, and Selenium by Hydride Generation Coupled with a Novel Solution-Cathode Glow Discharge-Atomic Emission Spectrometry Method.ANALYTICAL CHEMISTRY,88(23),11559-11567.
MLA	Huang, Chuchu,et al."Ultratrace Determination of Tin, Germanium, and Selenium by Hydride Generation Coupled with a Novel Solution-Cathode Glow Discharge-Atomic Emission Spectrometry Method".ANALYTICAL CHEMISTRY 88.23(2016):11559-11567.