Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation

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	Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
	Gu Y(古阳)1; Chang DL(常大路)1; Leng XB(冷雪冰)1; Gu YC(顾玉成)1; Shen QL(沈其龙)1
刊名	Organometallics
	2015
卷号	34 期号:12 页码:3065-3071
其他题名	Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
通讯作者	沈其龙
英文摘要	The preparation of the thermally stable, well-defined NHC-ligated difluoromethylated silver complexes la,b is described. The complexes were fully characterized, and the structural assignments were ambiguously further confirmed by single-crystal X-ray diffraction. Reactions of [(SIPr)Ag(CF2H)] with a variety of activated electrophiles such as diaryliodonium salts, vinyl(aryl)iodonium salts, aryldiazonium salts, and acid chlorides in the presence or absence of CuI occurred smoothly at room temperature to generate difluoromethylated compounds in good to excellent yields.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/acs.organomet.5b00350
语种	英语
WOS记录号	WOS:000356903100042
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39730]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	1.中科院上海有机化学研究所, 有机氟化学重点实验室 2.英国先正达
推荐引用方式 GB/T 7714	Gu Y,Chang DL,Leng XB,et al. Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation[J]. Organometallics,2015,34(12):3065-3071.
APA	古阳,常大路,冷雪冰,顾玉成,&沈其龙.(2015).Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation.Organometallics,34(12),3065-3071.
MLA	古阳,et al."Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation".Organometallics 34.12(2015):3065-3071.