CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines | |
Zhou W(周伟)1; Fan MY(樊梦阳)1; Yin JL(殷俊力)1; Jiang YW(蒋咏文)1; Ma DW(马大为)1 | |
刊名 | J. Am. Chem. Soc. |
2015 | |
卷号 | 137期号:37页码:11942-11945 |
其他题名 | 碘化亚铜/草酸二酰胺配体催化的芳基(杂芳基)氯代物与胺的偶联 |
通讯作者 | 马大为 |
英文摘要 | A class of oxalic diamides are found to be effective ligands for promoting CuI-catalyzed aryl amination with less reactive (hetero)aryl chlorides. The reaction proceeds at 120 degrees C with K3PO4 as the base in DMSO to afford a wide range of (hetero)aryl amines in good to excellent yields. The bis(N-aryl) substituted oxalamides are superior ligands to N-aryl-N'-alkyl substituted or bis(N-alkyl) substituted oxalamides. Both the electronic nature and the steric property of the aromatic rings in ligands are important for their efficiency. |
学科主题 | 生命有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jacs.5b08411 |
语种 | 英语 |
WOS记录号 | WOS:000361930000023 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39528] |
专题 | 上海有机化学研究所_生命有机化学国家重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 生命有机化学国家重点实验室 2.上海科技大学 |
推荐引用方式 GB/T 7714 | Zhou W,Fan MY,Yin JL,et al. CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines[J]. J. Am. Chem. Soc.,2015,137(37):11942-11945. |
APA | 周伟,樊梦阳,殷俊力,蒋咏文,&马大为.(2015).CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines.J. Am. Chem. Soc.,137(37),11942-11945. |
MLA | 周伟,et al."CuI/Oxalic Diamide Catalyzed Coupling Reaction of (Hetero)Aryl Chlorides and Amines".J. Am. Chem. Soc. 137.37(2015):11942-11945. |
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