Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones

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	Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones
	Wang D(王德)1; Wang GP(王国鹏)1; Sun YL(孙姚良)1; Zhu SF(朱守非)1; Wei Y(魏音)1; Zhou QL(周其林)1; Shi M(施敏)1
刊名	Chem. Sci.
	2015
卷号	6 期号:12 页码:7319-7325
其他题名	手性膦催化的高区域和高对映选择性环化反应研究-构建螺环骨架的苯并呋喃类化合物
通讯作者	魏音 ; 周其林 ; 施敏
英文摘要	The first regioselective catalytic asymmetric [3 + 2] cycloaddition of benzofuranone-derived olefins with allenoates and substituted allenoates has been developed in the presence of (R)-SITCP, affording different functionalized 3-spirocyclopentene benzofuran-2-ones in good yields with high enantioselectivities under mild conditions. The substrate scope has also been examined. The regioselective outcomes for this phosphine-catalyzed [3 + 2] cycloaddition reaction can be rationalized using DFT calculations.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5sc03135d
语种	英语
WOS记录号	WOS:000365225300076
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39672]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.南开大学
推荐引用方式 GB/T 7714	Wang D,Wang GP,Sun YL,et al. Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones[J]. Chem. Sci.,2015,6(12):7319-7325.
APA	王德.,王国鹏.,孙姚良.,朱守非.,魏音.,...&施敏.(2015).Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones.Chem. Sci.,6(12),7319-7325.
MLA	王德,et al."Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones".Chem. Sci. 6.12(2015):7319-7325.