Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity

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	Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity
	Liu YS(刘月盛); Wang L(王磊); Deng L(邓亮)
刊名	Organometallics
	2015
卷号	34 期号:17 页码:4401-4407
其他题名	氮杂环卡宾配体支撑的三配位铁烯基化合物的合成、结构和反应性质研究
通讯作者	邓亮
英文摘要	The reaction of [(IPr2Me2)(2)FePh2] with PhC equivalent to CPh furnished a three-coordinate iron(II) dialkenyl complex, [(IPr2Me2)Fe(sigma-CPh=CPh2)(2)] (1, IPr2Me2 = 1,3-diisopropy1-4,5-dimethylimidazol-2-ylidene), that represents a rare example of isolable low-coordinate iron alkenyl complexes with a high-spin ground state. Complex 1 was characterized by H-1 NMR spectroscopy, solution magnetic susceptibility measurement, Mossbauer spectroscopy, single-crystal X-ray diffraction study, and elemental analyses. A reactivity study revealed the reactions of 1 with PhCh(2)C1 to produce cross-coupling product Ph2C=CPhCh(2)Ph (2), with [Cp2Fe]-[BAr4F] to yield Ph2C=CPh CPh=CPh2 (3), and with CO, 2,6-dimethylphenyl isocyanide, and phenyl azide to produce novel iron(0) and iron(II) complexes 4-6 bearing triphenylvinyl-derived ligands. These transformations demonstrated the high reactivity of the low-coordinate iron alkenyl complex.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/acs.organomet.5b00632
语种	英语
WOS记录号	WOS:000361341800027
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39640]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Liu YS,Wang L,Deng L. Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity[J]. Organometallics,2015,34(17):4401-4407.
APA	刘月盛,王磊,&邓亮.(2015).Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity.Organometallics,34(17),4401-4407.
MLA	刘月盛,et al."Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity".Organometallics 34.17(2015):4401-4407.