Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes

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	Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes
	Tang XJ(汤鑫军)1; Han YL(韩玉林)1; Ma SM(麻生明)1
刊名	Org. Lett.
	2015
卷号	17 期号:5 页码:1176-1179
其他题名	碘化镉促进的从末端炔出发合成甲基取代的联烯的反应
通讯作者	麻生明
英文摘要	A cadmium iodide mediated tandem reaction involving amine and two molecules of terminal alkynes for the synthesis of trisubstituted allenes has been developed. By applying this protocol, methyl-substituted allenes may be obtained easily from two molecules of terminal alkynes and pyrrolidine via methyl ketoniminium and propargylic amine formation, 1,5-hydride transfer and beta-elimination.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/acs.orglett.5b00105
语种	英语
WOS记录号	WOS:000350841300030
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39574]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.复旦大学
推荐引用方式 GB/T 7714	Tang XJ,Han YL,Ma SM. Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes[J]. Org. Lett.,2015,17(5):1176-1179.
APA	汤鑫军,韩玉林,&麻生明.(2015).Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes.Org. Lett.,17(5),1176-1179.
MLA	汤鑫军,et al."Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes".Org. Lett. 17.5(2015):1176-1179.