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Structure of 2D Graphdiyne and Its Application in Energy Fields
Huang Chang-Shui1; Li Yu-Liang2
刊名ACTA PHYSICO-CHIMICA SINICA
2016-06-15
卷号32期号:6页码:1314-1329
关键词Graphdiyne Lithium storage Hydrogen storage Catalysis Solar cell
英文摘要This paper focuses on application of graphdiyne (GDY) in both energy storage and conversion fields, including the most recent theoretical and experimental progress. The unique three-dimensional pore structure formed by stacking of the GDY layer, make it possess the natural advantage which can be applied to lithium storage and hydrogen storage. Because of its lithium storage ability, GDY can be used in energy storage devices, such as lithium ion batteries and lithium ion capacitors. While with the hydrogen storage property, GDY can be used as a hydrogen storage material in fuel cells. By doping method, the performance of GDY for lithium and hydrogen storage can be further improved. Owing to acetylene units composed of sp hybridized carbon atoms and benzene rings composed of sp(2) hybridized carbon atoms, GDY possesses multiple conjugated electronic structures. Thus, its band gap can be regulated through many ways accompanied with existence of Dirac cones. This property means that GDY can not only be used as a high-activity non-metal catalyst in place of noble metal catalysts in photocatalysis, but it also plays a promotional role in the hole transport layer and electron transport layer of solar cells. All of the reported results including theoretical and experimental data reviewed here, show the great potential of GDY in energy field applications.
收录类别SCI
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/35550]  
专题化学研究所_有机固体实验室
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Huang Chang-Shui,Li Yu-Liang. Structure of 2D Graphdiyne and Its Application in Energy Fields[J]. ACTA PHYSICO-CHIMICA SINICA,2016,32(6):1314-1329.
APA Huang Chang-Shui,&Li Yu-Liang.(2016).Structure of 2D Graphdiyne and Its Application in Energy Fields.ACTA PHYSICO-CHIMICA SINICA,32(6),1314-1329.
MLA Huang Chang-Shui,et al."Structure of 2D Graphdiyne and Its Application in Energy Fields".ACTA PHYSICO-CHIMICA SINICA 32.6(2016):1314-1329.
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