Fe powder catalyzed highly efficient synthesis of alkenyl halides via direct coupling of alcohols and alkynes with aqueous HX as exogenous halide sources
Yang, Yong-Rong; Zhang, Qiang; Du, Feng-Tian; Ji, Jian-Xin
刊名TETRAHEDRON
2015
卷号71期号:25页码:4304-4311
关键词3 GEOMETRICAL-ISOMERS CARBON BOND FORMATION MEDIATED SYNTHESIS CONJUGATED (E,Z)-ALKADIENES STEREOSELECTIVE-SYNTHESIS STEREOSPECIFIC SYNTHESES CONVENIENT SYNTHESIS PHEROMONE BOMBYKOL 1-ALKENYLBORANES DERIVATIVES
通讯作者Ji, JX (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China.
产权排序1
合作状况国内
英文摘要A simple and efficient catalytic method for the synthesis of alkenyl halides via direct coupling of alcohols and alkynes using aqueous HX (X=Cl, Br) as halide sources has been developed under mild conditions in the presence of Fe powder (1 mol %). In comparison with the high loading of FeX3 in previously reported protocols, the present approach provides a remarkable attractive methodology to a diverse range of alkenyl halides due to the advantages of simple operation and low-level metal contamination. (C) 2015 Elsevier Ltd. All rights reserved.
学科主题Chemistry
类目[WOS]Chemistry, Organic
收录类别SCI
语种英语
内容类型期刊论文
源URL[http://210.75.237.14/handle/351003/27579]  
专题成都生物研究所_天然产物研究
推荐引用方式
GB/T 7714
Yang, Yong-Rong,Zhang, Qiang,Du, Feng-Tian,et al. Fe powder catalyzed highly efficient synthesis of alkenyl halides via direct coupling of alcohols and alkynes with aqueous HX as exogenous halide sources[J]. TETRAHEDRON,2015,71(25):4304-4311.
APA Yang, Yong-Rong,Zhang, Qiang,Du, Feng-Tian,&Ji, Jian-Xin.(2015).Fe powder catalyzed highly efficient synthesis of alkenyl halides via direct coupling of alcohols and alkynes with aqueous HX as exogenous halide sources.TETRAHEDRON,71(25),4304-4311.
MLA Yang, Yong-Rong,et al."Fe powder catalyzed highly efficient synthesis of alkenyl halides via direct coupling of alcohols and alkynes with aqueous HX as exogenous halide sources".TETRAHEDRON 71.25(2015):4304-4311.
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