Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System

	Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System
	Tang, Jian-Hong 1,2; Shao, Jiang-Yang 1; He, Yan-Qin 1; Wu, Si-Hai 1; Yao, Jiannian 1,2; Zhong, Yu-Wu 1,2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2016-07-18
卷号	22 期号:30 页码:10341-10345
关键词	density functional calculations electrochemistry electron transfer mixed-valence compounds ruthenium
英文摘要	A series of cyclometalated diruthenium complexes with a redox-active amine bridge were synthesized. Depending on the terminal ligands of the ruthenium components and the substituent on the amine unit, the one-electron-oxidized state can be either in the form of a weakly or strongly coupled mixed-valence diruthenium complex, a fully charge-delocalized three-center system, or a bridge-biased electrophore. This transition among different electronic forms was supported by electrochemistry, near-infrared absorption, electron paramagnetic resonance, and density functional theory analysis.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35208]
专题	化学研究所_光化学实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Tang, Jian-Hong,Shao, Jiang-Yang,He, Yan-Qin,et al. Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(30):10341-10345.
APA	Tang, Jian-Hong,Shao, Jiang-Yang,He, Yan-Qin,Wu, Si-Hai,Yao, Jiannian,&Zhong, Yu-Wu.(2016).Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System.CHEMISTRY-A EUROPEAN JOURNAL,22(30),10341-10345.
MLA	Tang, Jian-Hong,et al."Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System".CHEMISTRY-A EUROPEAN JOURNAL 22.30(2016):10341-10345.