Synthesis and Properties of Cost-effective Light-color and Highly Transparent Polyimide Films from Fluorine-containing Tetralin Dianhydride and Aromatic Diamines

	Synthesis and Properties of Cost-effective Light-color and Highly Transparent Polyimide Films from Fluorine-containing Tetralin Dianhydride and Aromatic Diamines
	Zhang, Xiu-min 1; Song, Yong-zhi 2; Liu, Jin-gang 2; Yang, Shi-yong 2
刊名	JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY
	2016
卷号	29 期号:1 页码:31-38
关键词	tetralin dianhydride fluoro polyimide optical properties thermal properties
英文摘要	A novel fluoro-containing tetralin dianhydride, 3,4-dicarboxy-1,2,3,4-tetrahydro-6-fluoro-1-naphthalene succinic dianhydride (FTDA) was successfully prepared via a cost-effective route with maleic anhydride and p-fluorostyrene as the starting materials. A series of semi-alicyclic polyimides (PIs) have been synthesized from FTDA and aromatic diamines, including 4,4'-oxydianiline (ODA) for PI-a, 1,4-bis(4-aminophenoxy)benzene (APB) for PI-b, 2,2'-bis[(4-aminophenoxy)phenyl]propane (BAPP) for PI-c, and 2,2'-bis[(4-aminophenoxy)phenyl]hexafluoropropane (BDAF) for PI-d via a one-step high-temperature imidization procedure. The derived PI resins are easily soluble in polar aprotic solvents, such as N-methyl-2-pyrrolidone (NMP) and N,N-dimethylacetamide (DMAc). Flexible and tough PI films were cast from their solutions in NMP at a solid content of 15 wt%. The prepared PI films exhibited good optical transparency in the visible light region with the transmittance higher than 80% at the wavelength of 450 nm. In addition, the PI films exhibited good thermal stability with the 5% weight loss temperatures >402 degrees C and glass transition temperatures >230 degrees C.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35215]
专题	化学研究所_高技术材料实验室
作者单位	1.Beijing Jiaotong Univ, Sch Elect Engn, Beijing 100044, Peoples R China 2.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xiu-min,Song, Yong-zhi,Liu, Jin-gang,et al. Synthesis and Properties of Cost-effective Light-color and Highly Transparent Polyimide Films from Fluorine-containing Tetralin Dianhydride and Aromatic Diamines[J]. JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY,2016,29(1):31-38.
APA	Zhang, Xiu-min,Song, Yong-zhi,Liu, Jin-gang,&Yang, Shi-yong.(2016).Synthesis and Properties of Cost-effective Light-color and Highly Transparent Polyimide Films from Fluorine-containing Tetralin Dianhydride and Aromatic Diamines.JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY,29(1),31-38.
MLA	Zhang, Xiu-min,et al."Synthesis and Properties of Cost-effective Light-color and Highly Transparent Polyimide Films from Fluorine-containing Tetralin Dianhydride and Aromatic Diamines".JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY 29.1(2016):31-38.