Reversible molecular adsorption of free-standing nano-composite film made from boehmite and poly(acrylic acid)
Yuan, Qian1,2; Zhang, Xuejian1,2; Gong, Ying1,2; Ma, Ying3; Xu, Jian4; Yang, Shuguang1,2
刊名COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
2016-10-20
卷号507页码:210-217
关键词Layer-by-layer assembly Nano-composite film Cross-linking Free-standing Reversible molecular adsorption
英文摘要A nano-composite film with reversible small molecules adsorption behavior was fabricated via layer-by layer (LbL) assembly of boehmite nano-particles and weak polyelectrolyte poly(acrylic acid) (PAA). Both electrostatic force and hydrogen bonding interaction were involved to fabricate the nano-composite thin film. Boehmite/PAA nano-composite thin film was further cross-linked with thermal treatment, which enhanced the stability of the film. When immersed into the basic solution, the thermal cross-linked film wholly detached from the substrate. And the dynamic cross-links such as hydrogen bonding and electrostatic interaction endowed the free-standing film reversible swelling/shrinking ability in response to pH variations at least five times. Furthermore, the free-standing Boehmite/PAA film showed reversible rhodamine B (RB) adsorption behavior, which could be utilized for controlled loading and releasing. (C) 2016 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/35324]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
2.Donghua Univ, Coll Mat Sci & Engn, Shanghai 201620, Peoples R China
3.Donghua Univ, Coll Text, Shanghai 201620, Peoples R China
4.Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Yuan, Qian,Zhang, Xuejian,Gong, Ying,et al. Reversible molecular adsorption of free-standing nano-composite film made from boehmite and poly(acrylic acid)[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2016,507:210-217.
APA Yuan, Qian,Zhang, Xuejian,Gong, Ying,Ma, Ying,Xu, Jian,&Yang, Shuguang.(2016).Reversible molecular adsorption of free-standing nano-composite film made from boehmite and poly(acrylic acid).COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,507,210-217.
MLA Yuan, Qian,et al."Reversible molecular adsorption of free-standing nano-composite film made from boehmite and poly(acrylic acid)".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 507(2016):210-217.
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