In-situ Synthesis and Discharge Performance of Ni-NiCl2 Composite as Cathode Materials for Thermal Batteries | |
Chu Ying1; Li Yun-Wei2; Wu Qi-Bing2; Hu Jing1; Tian Qian-Qiu2; Hu He-Long1; Zhu Yong-Ping1 | |
刊名 | JOURNAL OF INORGANIC MATERIALS |
2016-09-20 | |
卷号 | 31期号:9页码:992-996 |
关键词 | thermal batteries cathode material Ni-NiCl2 Composite: in-situ synthesis discharge performance |
ISSN号 | 1000-324X |
英文摘要 | As a high potential compound, NiCl2 is an ideal anode material for high powder thermal battery, but its small specific surface area and poor conductivity hinder the application in thermal battery. In present study, The Ni-NiCl2 composite with high specific surface area and conductivity was prepared by sublimation and in-situ synthesis, as cathode materials for thermal batteries. The precursor material NiCl2 center dot 6H(2)O was dried to dehydrate and sublimated at 850 similar to 900 degrees C in Ar atmosphere successively. And then the yellow sublimed powder was reduced at 300 similar to 500 degrees C in Ar + H-2 atmosphere for 1 h. Finally, the Ni and NiCl2 composite powders were formed. Thermoanalysis, crystal structure, in-situ synthesis process and electrochemical performance of the powders were analyzed. The results show that NiCl2 crystal grows along the direction perpendicular to c axis and formed a layered structure of 200-300 mu m in the sublimation process. The resistivity of Ni-NiCl2 composite is reduced with the increase of elemental Ni content. The discharge curve of LiSi vertical bar LiCl-LiBr-LiF vertical bar NiCl2 thermal batteries with Ni-NiCl2 (5wt% elemental Ni) as anode material at 1000 mA/cm(2) is more stable and has a shorter activation time, as compared to the discharge curve with pure NiCl2 as anode material. |
WOS标题词 | Science & Technology ; Technology |
类目[WOS] | Materials Science, Ceramics |
研究领域[WOS] | Materials Science |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000383397000015 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21340] |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 2.Meiling Power Co Ltd, Zunyi 563003, Peoples R China |
推荐引用方式 GB/T 7714 | Chu Ying,Li Yun-Wei,Wu Qi-Bing,et al. In-situ Synthesis and Discharge Performance of Ni-NiCl2 Composite as Cathode Materials for Thermal Batteries[J]. JOURNAL OF INORGANIC MATERIALS,2016,31(9):992-996. |
APA | Chu Ying.,Li Yun-Wei.,Wu Qi-Bing.,Hu Jing.,Tian Qian-Qiu.,...&Zhu Yong-Ping.(2016).In-situ Synthesis and Discharge Performance of Ni-NiCl2 Composite as Cathode Materials for Thermal Batteries.JOURNAL OF INORGANIC MATERIALS,31(9),992-996. |
MLA | Chu Ying,et al."In-situ Synthesis and Discharge Performance of Ni-NiCl2 Composite as Cathode Materials for Thermal Batteries".JOURNAL OF INORGANIC MATERIALS 31.9(2016):992-996. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论