Leaching of vanadium, sodium, and silicon from molten V-Ti-bearing slag obtained from low-grade vanadium-bearing titanomagnetite | |
Zhu, Yuan-yuan1,2,3; Yi, Ling-yun2,3; Zhao, Wei2,3; Chen, De-sheng2,3; Zhao, Hong-xin2,3; Qi, Tao2,3 | |
刊名 | INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS |
2016-08-01 | |
卷号 | 23期号:8页码:898-905 |
关键词 | titanomagnetite vanadium metallurgy leaching kinetics sodium silicon leaching rate |
ISSN号 | 1674-4799 |
英文摘要 | The water leaching process of vanadium, sodium, and silicon from molten vanadium-titanium-bearing (V-Ti-bearing) slag obtained from low-grade vanadium-bearing titanomagnetite was investigated systematically. The results show that calcium titanate, sodium aluminosilicate, sodium oxide, silicon dioxide and sodium vanadate are the major components of the molten V-Ti-bearing slag. The experimental results indicate that the liquid-solid (L/S) mass ratio significantly affects the leaching process because of the respective solubilities and diffusion rates of the components. A total of 83.8% of vanadium, 72.8% of sodium, and 16.1% of silicon can be leached out via a triple counter-current leaching process under the optimal conditions of a particle size below 0.074 mm, a temperature of 90A degrees C, a leaching time of 20 min, an L/S mass ratio of 4:1, and a stirring speed of 300 r/min. The kinetics of vanadium leaching is well described by an internal diffusion-controlled model and the apparent activation energy is 11.1 kJ/mol. The leaching mechanism of vanadium was also analyzed. |
WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
类目[WOS] | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
研究领域[WOS] | Materials Science ; Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
关键词[WOS] | EXTRACTION ; OXIDATION ; RECOVERY ; ACID |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000381134000005 |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21286] |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Yuan-yuan,Yi, Ling-yun,Zhao, Wei,et al. Leaching of vanadium, sodium, and silicon from molten V-Ti-bearing slag obtained from low-grade vanadium-bearing titanomagnetite[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,2016,23(8):898-905. |
APA | Zhu, Yuan-yuan,Yi, Ling-yun,Zhao, Wei,Chen, De-sheng,Zhao, Hong-xin,&Qi, Tao.(2016).Leaching of vanadium, sodium, and silicon from molten V-Ti-bearing slag obtained from low-grade vanadium-bearing titanomagnetite.INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,23(8),898-905. |
MLA | Zhu, Yuan-yuan,et al."Leaching of vanadium, sodium, and silicon from molten V-Ti-bearing slag obtained from low-grade vanadium-bearing titanomagnetite".INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS 23.8(2016):898-905. |
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