Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

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	Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene
	Li, CY; Yan, L; Lu, LL; Xiong, K; Wang, WL; Jiang, M; Liu, J; Song, XG; Zhan, ZP; Jiang, Z
刊名	GREEN CHEMISTRY
	2016
卷号	18 期号:10 页码:2995—3005
关键词	SUPERCRITICAL CARBON-DIOXIDE GAS-PHASE HYDROFORMYLATION RHODIUM-BIPHEPHOS-CATALYST MODIFIED RH/SIO2 CATALYSTS IN-SITU FORMATION IONIC-LIQUID HETEROGENEOUS CATALYSTS SELECTIVE HYDROFORMYLATION ASYMMETRIC HYDROFORMYLATION PROPYLENE CARBONATE
ISSN号	1463-9262
通讯作者	Yan, L ; Ding, YJ (reprint author), Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China. ; Ding, YJ (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.
英文摘要	A vinyl functionalized biphephos ligand with high steric hindrance was copolymerized with tris(4-vinphenyl)phosphane and other ligands to afford efficient porous organic copolymers (POPs) through the solvothermal synthesis technique. By employing the copolymer self-supported heterogeneous Rh/CPOL-bp&P catalysts, the hydroformylation of propene to linear-butaldehyde can be performed efficiently in a continuous fixed-bed reactor with high regioselectivity (l/b > 24), activity (TOF > 1200 h(-1)) and stability (over 1000 h) under mild conditions (70 degrees C, 0.5 MPa), which represents a substantial improvement in the efficiency of this important industrial process. EXAFS and HAADF-STEM showed that the Rh was a single atom dispersion, which explained well the high efficiency of the Rh/CPOL-bp&P catalysts. Compared with liquid-liquid biphasic (LLB) and ionic liquid (IL) systems, this highly efficient solvent free system has the advantages of simple operability, and almost no waste emission, which meets the demands of green industrial processing.
收录类别	SCI
语种	英语
WOS记录号	WOS:000376082400012
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/25832]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Li, CY,Yan, L,Lu, LL,et al. Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene[J]. GREEN CHEMISTRY,2016,18(10):2995—3005.
APA	Li, CY.,Yan, L.,Lu, LL.,Xiong, K.,Wang, WL.,...&Ding, YJ.(2016).Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene.GREEN CHEMISTRY,18(10),2995—3005.
MLA	Li, CY,et al."Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene".GREEN CHEMISTRY 18.10(2016):2995—3005.