Fabrication of graphene-encapsulated Na3V2(PO4)(3) as high-performance cathode materials for sodium-ion batteries

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	Fabrication of graphene-encapsulated Na3V2(PO4)(3) as high-performance cathode materials for sodium-ion batteries
	Tao, S; Wang, XB; Cui, PX; Wang, Y; Haleem, YA; Wei, SH; Huang, WF; Song, L; Chu, WS
刊名	RSC ADVANCES
	2016
卷号	6 期号:49 页码:43591—43597
关键词	CARBON-COATED NA3V2(PO4)(3) ELECTROCHEMICAL INTERCALATION ELECTRODE MATERIAL HIGH-POWER COMPOSITE OXIDE NANOPARTICLES ENHANCEMENT STORAGE
ISSN号	2046-2069
通讯作者	Song, L ; Chu, WS (reprint author), Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230026, Anhui, Peoples R China.
英文摘要	Na3V2(PO4)(3) (NVP) has been in the spotlight as a potential candidate of next generation batteries to overcome the limitation of lithium resources on Earth. Here a thin-layer graphene-encapsulated NVP composite (NVP/G) was synthesized by self-assembly of surface modified NVP and graphene oxide and then followed by reduction to compensate for the intrinsic low electronic conductivity of NVP and strengthen its structure stability. The as-synthesized hybrid composite as a cathode for sodium-ion batteries (SIBs) exhibits excellent high specific capacity and superior rate performance with discharge capacities of 115.2 mA h g(-1) at 0.2 C and 70.1 mA h g(-1) at 30 C, It also shows an excellent cycling stability with about 86.0% capacity retention at 5 C after 300 cycles. Ex situ X-ray absorption spectroscopy (XAS) characterization confirmes the local geometrical environment around vanadium is highly conserved during the sodiation/desodiation process, associated with an electrochemically active V3+/V4+ redox couple. Hence the as-prepared hybrid composite can be considered as a promising cathode material for high-rate SIBs, thanks to the effect interface interaction between NVP nanoparticle sand graphene films.
收录类别	SCI
语种	英语
WOS记录号	WOS:000375611100095
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/25724]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Tao, S,Wang, XB,Cui, PX,et al. Fabrication of graphene-encapsulated Na3V2(PO4)(3) as high-performance cathode materials for sodium-ion batteries[J]. RSC ADVANCES,2016,6(49):43591—43597.
APA	Tao, S.,Wang, XB.,Cui, PX.,Wang, Y.,Haleem, YA.,...&Chu, WS.(2016).Fabrication of graphene-encapsulated Na3V2(PO4)(3) as high-performance cathode materials for sodium-ion batteries.RSC ADVANCES,6(49),43591—43597.
MLA	Tao, S,et al."Fabrication of graphene-encapsulated Na3V2(PO4)(3) as high-performance cathode materials for sodium-ion batteries".RSC ADVANCES 6.49(2016):43591—43597.