Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones
Zhou, Zhao-Zhao1; Zheng, Lan1; Yan, Xiao-Biao1; Jin, Dong-Po1; He, Yu-Tao1; Liang YM(梁永民)1,2
刊名Organic and Biomolecular Chemistry
2016
卷号14期号:19页码:4507-4510
ISSN号1477-0520
通讯作者梁永民
英文摘要

A silver-promoted oxidative cascade cyclization with a phosphorylation/1,5-aryl migration/desulfonylation/dearomatization process is presented here, providing an efficient method to synthesize azaspiro[4.5]decenones with high regioselectivity. The cinnamamidyl radical, which has rarely been reported before, plays a key role in this reaction.

学科主题材料科学与物理化学
收录类别SCI
资助信息the National Natural Science Foundation (NSF 21272101;21472073);the "111" Project (J1103307);Program for Changjiang Scholars and Innovative Research Team in University (IRT1138)
语种英语
WOS记录号WOS:000376111000019
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/20105]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Zhao-Zhao,Zheng, Lan,Yan, Xiao-Biao,et al. Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones[J]. Organic and Biomolecular Chemistry,2016,14(19):4507-4510.
APA Zhou, Zhao-Zhao,Zheng, Lan,Yan, Xiao-Biao,Jin, Dong-Po,He, Yu-Tao,&Liang YM.(2016).Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones.Organic and Biomolecular Chemistry,14(19),4507-4510.
MLA Zhou, Zhao-Zhao,et al."Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones".Organic and Biomolecular Chemistry 14.19(2016):4507-4510.
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