Bioinspired Total Synthesis of Gymnothelignan N | |
Li HL(李辉林)1; Zhang, Yuanyuan1; Xie XG(谢新刚)1; Ma, Haichen1; Zhao CG(赵常贵)1; Zhao, Gaoyuan1; She XG(厍学功)1,2 | |
刊名 | Organic Letters |
2014 | |
卷号 | 16期号:17页码:4440-4443 |
ISSN号 | 1523-7060 |
通讯作者 | 厍学功 |
英文摘要 | Bioinspired total synthesis of gymnothelignan N was accomplished in 13 steps and 6.7% overall yield. The synthesis features a syn Evans aldol reaction, an intramolecular hydrogenative dehydration reaction, and a phenol oxidative dearomatization/Friedel-Crafts reaction, which provides a new plausible biosynthetic pathway for the gymnothelignans and other symbiotic members. Meanwhile, another tetrahydrofuran-type lignan beilschmin A was also synthesized. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the NSFC (21125207;21372103);the MOST (2010CB833200);the SRFDP (20130211110018);the FRFCU (lzujbky-2014-240) |
语种 | 英语 |
WOS记录号 | WOS:000341344600024 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/20258] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Lanzhou Univ, Dept Chem, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Li HL,Zhang, Yuanyuan,Xie XG,et al. Bioinspired Total Synthesis of Gymnothelignan N[J]. Organic Letters,2014,16(17):4440-4443. |
APA | Li HL.,Zhang, Yuanyuan.,Xie XG.,Ma, Haichen.,Zhao CG.,...&She XG.(2014).Bioinspired Total Synthesis of Gymnothelignan N.Organic Letters,16(17),4440-4443. |
MLA | Li HL,et al."Bioinspired Total Synthesis of Gymnothelignan N".Organic Letters 16.17(2014):4440-4443. |
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