Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate | |
Ma YN(马艳娜)1; Yang SD(杨尚东)1,2 | |
刊名 | Chemical Record
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2016 | |
卷号 | 16期号:2页码:977-986 |
关键词 | asymmetric C-H functionalization asymmetric Suzuki-Miyaura cross-coupling chiral auxiliaries menthyl phenylphosphinate phosphine ligands |
ISSN号 | 1527-8999 |
英文摘要 | This review describes new methods for the synthesis of chiral monophosphine ligands with menthyl phenylphosphinate as a chiral auxiliary through asymmetric Suzuki-Miyaura cross-coupling reactions and asymmetric C–H functionalization. The chiral menthyl phenylphosphinate as a chiral auxiliary is easy to prepare and the menthyl group can easily be transformed into other functional groups, with the chiral center synchronously remaining. These methodologies provide highly efficient and practical strategies for the synthesis of novel axially chiral biaryl monophosphine oxides and their corresponding phosphines. Meanwhile, these reactions are easy to handle and exhibit wide scope for substrates with excellent diastereomeric ratios. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the NSFC (Nos. 21272100;21472076) |
语种 | 英语 |
WOS记录号 | WOS:000374765700026 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/20096] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Ma YN,Yang SD. Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate[J]. Chemical Record,2016,16(2):977-986. |
APA | Ma YN,&Yang SD.(2016).Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate.Chemical Record,16(2),977-986. |
MLA | Ma YN,et al."Asymmetric Synthesis of Chiral Atropisomeric Bis-Aryl Organophosphorus from Menthyl H-Phosphinate".Chemical Record 16.2(2016):977-986. |
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