Catalytic oxidation of toluene over active MnO (x) catalyst prepared via an alkali-promoted redox precipitation method

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	Catalytic oxidation of toluene over active MnO (x) catalyst prepared via an alkali-promoted redox precipitation method
	Wang, Lei 1,2; Zhang, Chuanhui 2; Huang, He 2; Li, Xuebing 2; Zhang, Wei 1; Lu, Mohong 1; Li, Mingshi 1
刊名	REACTION KINETICS MECHANISMS AND CATALYSIS
	2016-08-01
卷号	118 期号:2 页码:605-619
关键词	VOCs MnOx Redox precipitation Reducibility Average oxidation state
英文摘要	MnO (x) catalysts were contrastively prepared by an alkali-promoted redox precipitation strategy (MnO (x) -RP) and a conventional citrate sol-gel method (MnO (x) -SG), and tested for the catalytic oxidation of toluene, where MnO (x) -RP exhibited higher catalytic activity, excellent catalytic durability under dry conditions and good regeneration ability under humid conditions. The characterizations results indicated that different crystalline phases but similar textual properties (specific surface area, porosity and morphology) were observed over MnO (x) -RP and MnO (x) -SG catalysts, while MnO (x) -RP presented significantly higher low-temperature reducibility and average oxidation state of Mn as well as higher abundance of surface adsorbed oxygen species compared with MnO (x) -SG, thus beneficially resulting in its superior catalytic activity in the reaction.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	MANGANESE OXIDE CATALYSTS ; VOLATILE ORGANIC-COMPOUNDS ; ORDERED MACROPOROUS LAMNO3 ; HIGH-EFFICIENCY CATALYSTS ; PEROVSKITE CATALYST ; ROOM-TEMPERATURE ; HIGH-PERFORMANCE ; CARBON-MONOXIDE ; COMBUSTION ; VOCS
收录类别	SCI
语种	英语
WOS记录号	WOS:000379345000018
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/8393]
专题	青岛生物能源与过程研究所_多相催化转化团队
作者单位	1.Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式 GB/T 7714	Wang, Lei,Zhang, Chuanhui,Huang, He,et al. Catalytic oxidation of toluene over active MnO (x) catalyst prepared via an alkali-promoted redox precipitation method[J]. REACTION KINETICS MECHANISMS AND CATALYSIS,2016,118(2):605-619.
APA	Wang, Lei.,Zhang, Chuanhui.,Huang, He.,Li, Xuebing.,Zhang, Wei.,...&Li, Mingshi.(2016).Catalytic oxidation of toluene over active MnO (x) catalyst prepared via an alkali-promoted redox precipitation method.REACTION KINETICS MECHANISMS AND CATALYSIS,118(2),605-619.
MLA	Wang, Lei,et al."Catalytic oxidation of toluene over active MnO (x) catalyst prepared via an alkali-promoted redox precipitation method".REACTION KINETICS MECHANISMS AND CATALYSIS 118.2(2016):605-619.