Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts
Chen, Dawei1,2; Liang, Fengbing1; Feng, Dexin1; Du, Fanglin2; Zhao, Guang1; Liu, Huizhou1; Xian, Mo1
刊名CATALYSIS COMMUNICATIONS
2016-09-05
卷号84页码:159-162
关键词Lignocellulose Cellulose Xylan HMF Furfural
英文摘要Bifunctional lignosulfonate-based catalysts (LS-M) with Lewis acid and basic sites were designed and prepared by immobilizing metal ions on lignosulfonate. Catalysts were characterized by XRD, XPS, SEM, EDX, TEM, TGA, NH3/CO2-TPD and FTIR, and applied in transformation of carbohydrate biomass to furan derivatives (HMF/furfural) in mixed water/THF systems. With LS-Cr as catalyst, the optimized yields of HMF from cellulose, glucose and mannose were 46.3%, 60.4% and 68.8%, and that of furfural from xylan, xylose and arabinose were 40.2%, 73.1% and 51.6%, respectively. The catalysts could be easily recycled with negligible wastage of the active metal ions. (C) 2016 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]IONIC LIQUIDS ; ACID ; CONVERSION ; LIGNIN ; ISOMERIZATION ; CHEMICALS ; FRUCTOSE ; GLUCOSE ; XYLOSE ; WATER
收录类别SCI
语种英语
WOS记录号WOS:000381534300036
内容类型期刊论文
源URL[http://ir.qibebt.ac.cn/handle/337004/8502]  
专题青岛生物能源与过程研究所_材料生物技术研究中心
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol China, CAS Key Lab Biobased Mat, Beijing 100864, Peoples R China
2.Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Nanostruct Mat, Qingdao 266042, Peoples R China
推荐引用方式
GB/T 7714
Chen, Dawei,Liang, Fengbing,Feng, Dexin,et al. Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts[J]. CATALYSIS COMMUNICATIONS,2016,84:159-162.
APA Chen, Dawei.,Liang, Fengbing.,Feng, Dexin.,Du, Fanglin.,Zhao, Guang.,...&Xian, Mo.(2016).Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts.CATALYSIS COMMUNICATIONS,84,159-162.
MLA Chen, Dawei,et al."Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts".CATALYSIS COMMUNICATIONS 84(2016):159-162.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace