AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes

	AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes
	Gao B(高兵); Zhao YC(赵延川); Ni CF(倪传法); Hu JB(胡金波)
刊名	Org. Lett.
	2014
卷号	16 期号:1 页码:102-105
其他题名	偕二氟烯烃在银调控下的氟化自偶联反应
通讯作者	胡金波
英文摘要	A novel silver(I)-fluoride-mediated homocoupling reaction of beta,beta-difluorostyrene derivatives is described. The transformation is initiated via nucleophilic addition of silver(I) fluoride to beta,beta-difluorostyrenes, which is followed by dimerization of the corresponding benzylsilver intermediates. The reaction shows good substrate scope, functional group tolerance, and represents the first report on the reactivity of (alpha-trifluoromethyl)benzylsilver species.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol403083e
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38814]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Gao B,Zhao YC,Ni CF,et al. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes[J]. Org. Lett.,2014,16(1):102-105.
APA	高兵,赵延川,倪传法,&胡金波.(2014).AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes.Org. Lett.,16(1),102-105.
MLA	高兵,et al."AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes".Org. Lett. 16.1(2014):102-105.